Surface Charge Density and Steric Repulsion in Polyelectrolyte–Surfactant Coacervation
Solutions of oppositely charged polyelectrolytes and surfactants can undergo phase
separation, in a charge-driven process known as complex coacervation. These materials are …
separation, in a charge-driven process known as complex coacervation. These materials are …
Structure and dynamics of hybrid colloid–polyelectrolyte coacervates: Insights from molecular simulations
Electrostatic interactions in polymeric systems are responsible for a wide range of liquid–
liquid phase transitions that are of importance for biology and materials science. Such …
liquid phase transitions that are of importance for biology and materials science. Such …
The effect of salt on the complex coacervation of vinyl polyelectrolytes
Complex coacervation is an electrostatically-driven phase separation phenomenon that is
utilized in a wide range of everyday applications and is of great interest for the creation of …
utilized in a wide range of everyday applications and is of great interest for the creation of …
Hybrid field theory and particle simulation model of polyelectrolyte–surfactant coacervation
JJ Madinya, CE Sing - Macromolecules, 2022 - ACS Publications
Solutions of oppositely charged polyelectrolytes and surfactants have been widely studied
for a variety of applications; they play an important role in the formulation of personal care …
for a variety of applications; they play an important role in the formulation of personal care …
Development of the modern theory of polymeric complex coacervation
CE Sing - Advances in colloid and interface science, 2017 - Elsevier
Oppositely charged polymers can undergo the process of complex coacervation, which
refers to a liquid–liquid phase separation driven by electrostatic attraction. These materials …
refers to a liquid–liquid phase separation driven by electrostatic attraction. These materials …
Phase behavior and molecular thermodynamics of coacervation in oppositely charged polyelectrolyte/surfactant systems: A cationic polymer JR 400 and anionic …
Coacervation in mixtures of polyelectrolytes and surfactants with opposite charge is common
in nature and is also technologically important to consumer health care products. To …
in nature and is also technologically important to consumer health care products. To …
Future directions in physiochemical modeling of the thermodynamics of polyelectrolyte coacervates
We review theories of polyelectrolyte (PE) coacervation, which is the spontaneous
association of oppositely charged units of PEs and phase separation into a polymer‐dense …
association of oppositely charged units of PEs and phase separation into a polymer‐dense …
Complexation and coacervation of polyelectrolytes with oppositely charged colloids
E Kizilay, AB Kayitmazer, PL Dubin - Advances in colloid and interface …, 2011 - Elsevier
Polyelectrolyte-colloid coacervation could be viewed as a sub-category of complex
coacervation, but is unique in (1) retaining the structure and properties of the colloid, and (2) …
coacervation, but is unique in (1) retaining the structure and properties of the colloid, and (2) …
Complex coacervation of statistical polyelectrolytes: role of monomer sequences and formation of inhomogeneous coacervates
Advances in synthetic chemistry have led to greater control over the sequence of polymeric
materials, and the ability to create patterns whose complexity is reminiscent of that of …
materials, and the ability to create patterns whose complexity is reminiscent of that of …
Transfer matrix model of pH effects in polymeric complex coacervation
AR Knoerdel, WC Blocher McTigue… - The Journal of Physical …, 2021 - ACS Publications
Oppositely charged polyelectrolytes can undergo an associative phase separation, in a
process known as polymeric complex coacervation. This phenomenon is driven by the …
process known as polymeric complex coacervation. This phenomenon is driven by the …