Interplay between free surface and solid interface nucleation on two-step crystallization of poly (ethylene terephthalate) thin films studied by fast scanning calorimetry

S Luo, X Kui, E Xing, X Wang, G Xue, C Schick… - …, 2018 - ACS Publications
Under confinement, unique features of crystallization arise, among which the slowing down
and accelerating crystallization on cooling are both reported. The controversy can be …

Stepwise crystallization and the layered distribution in crystallization kinetics of ultra-thin poly (ethylene terephthalate) film

B Zuo, J Xu, S Sun, Y Liu, J Yang, L Zhang… - The Journal of Chemical …, 2016 - pubs.aip.org
Crystallization is an important property of polymeric materials. In conventional viewpoint, the
transformation of disordered chains into crystals is usually a spatially homogeneous process …

Enhanced crystallization kinetics in poly (ethylene terephthalate) thin films evidenced by infrared spectroscopy

M Bertoldo, M Labardi, C Rotella, S Capaccioli - Polymer, 2010 - Elsevier
The cold crystallization process in poly (ethylene terephthalate)(PET) spin-coated ultrathin
films was studied by infrared spectroscopy. The conformational change associated to the …

Surface and bulk morphology of cold-crystallized poly (ethylene terephthalate)

Q Zia, E Ingolič, R Androsch - Colloid and Polymer Science, 2010 - Springer
The morphology/habit of crystals of cold-crystallized poly (ethylene terephthalate)(PET) has
been evaluated using scanning and transmission electron microscopy and using atomic …

Crystallization of thin polymer layers confined between two adsorbing walls

B Vanroy, M Wubbenhorst, S Napolitano - ACS macro letters, 2013 - ACS Publications
Confined at the nanoscale level, polymers crystallize much slower than in bulk, and in some
cases, the formation of ordered structure is inhibited within extremely long experimental time …

Reflection–absorption infrared spectroscopy investigation of the crystallization kinetics of poly (ethylene terephthalate) ultrathin films

Y Zhang, Y Lu, Y Duan, J Zhang… - Journal of Polymer …, 2004 - Wiley Online Library
Reflection–absorption infrared spectroscopy was used to study the crystallization behavior
of poly (ethylene terephthalate)(PET) ultrathin films. The crystallinity of ultrathin films was …

Surface crystallization of poly (ethylene terephtalate) studied by atomic force microscopy

VM De Cupere, PG Rouxhet - Polymer, 2002 - Elsevier
Poly (ethylene terephtalate)(PET) crystallization was shown by atomic force microscopy
(AFM) to occur at 85° C in the first few nanometers near the polymer–air interface. The …

Thickness of the surface mobile layer with accelerated crystallization kinetics in poly (ethylene terephthalate) films: Direct measurement and analysis

J Xu, Y Li, X Wu, B Zuo, X Wang, W Zhang… - …, 2018 - ACS Publications
Ultrathin polymer films exhibit a liquidlike mobile surface layer near the free surface, which
plays an important role in the size-dependent physical properties of polymer nanomaterials …

Tip-splitting crystal growth observed in crystallization from thin films of poly (ethylene terephthalate)

Y Sakai, M Imai, K Kaji, M Tsuji - Journal of crystal growth, 1999 - Elsevier
A novel crystal morphology called terrace appearing in the crystallization of poly (ethylene
terephthalate)(PET) is studied. This morphology is confirmed to be inherent to the polymer …

Kinetics of surface crystallization in thin films of poly (ethylene terephthalate)

PC Jukes, A Das, M Durell, D Trolley… - …, 2005 - ACS Publications
In-situ grazing incidence X-ray diffraction has been used to investigate the kinetics of
crystallization at the surface of thin films of poly (ethylene terephthalate)(PET). By varying the …