The optimized Fenton-like activity of Fe single-atom sites by Fe atomic clusters–mediated electronic configuration modulation

F Mo, C Song, Q Zhou, W Xue… - Proceedings of the …, 2023 - National Acad Sciences
The performance optimization of isolated atomically dispersed metal active sites is critical
but challenging. Here, TiO2@ Fe species-NC catalysts with Fe atomic clusters (ACs) and …

Modulating the Electronic Coordination Configuration and d-Band Center in Homo-Diatomic Fe2N6 Catalysts for Enhanced Peroxymonosulfate Activation

J Li, Y Zou, Z Li, S Fu, Y Lu, S Li, X Zhu… - ACS Applied Materials …, 2022 - ACS Publications
The electronic coordination configuration of metal active sites and the reaction mechanism
were investigated by constructing homo-diatomic Fe sites for visible-light-assisted …

Identification of Fenton-like active Cu sites by heteroatom modulation of electronic density

X Zhou, MK Ke, GX Huang, C Chen… - Proceedings of the …, 2022 - National Acad Sciences
Developing heterogeneous catalysts with atomically dispersed active sites is vital to boost
peroxymonosulfate (PMS) activation for Fenton-like activity, but how to controllably adjust …

Microenvironment modulation of cobalt single-atom catalysts for boosting both radical oxidation and electron-transfer process in Fenton-like system

K Yin, R Wu, Y Shang, D Chen, Z Wu, X Wang… - Applied Catalysis B …, 2023 - Elsevier
Two coordination structures (Co-N 4 or Co-N 3) of cobalt single-atom catalysts (Co-SACs)
were prepared by using the chitosan as starting precursor to evaluate the modulated …

Regulating spin state of Fe active sites by the P-doping strategy for enhancing peroxymonosulfate activation

Z Yang, X Yang, G An, D Wang - Applied Catalysis B: Environmental, 2023 - Elsevier
Optimization of Fe-based heterogeneous catalyst for enhancing PMS activation was studies
by an electronic structure regulation strategy. The single atom and nano-particle Fe-catalysts …

Fe containing template derived atomic Fe–N–C to boost Fenton-like reaction and charge migration analysis on highly active Fe–N 4 sites

Y Gao, X Duan, B Li, Q Jia, Y Li, X Fan… - Journal of Materials …, 2021 - pubs.rsc.org
Persulfate-based advanced oxidation processes are promising technologies to solve water
pollution. In this work, single iron atoms are anchored on three-dimensional N-doped carbon …

Engineering single-atom Fe-Pyridine N4 sites to boost peroxymonosulfate activation for antibiotic degradation in a wide pH range

X Xu, F Zhan, J Pan, L Zhou, L Su, W Cen, W Li, C Tian - Chemosphere, 2022 - Elsevier
Single-atom Fe catalysts have shown great potential for Fenton-like technology in organic
pollutant decomposition. However, the underlying reaction pathway and the identification of …

Switching the reaction mechanisms and pollutant degradation routes through active center size-dependent Fenton-like catalysis

X Wang, Z Xiong, H Shi, Z Wu, B Huang… - Applied Catalysis B …, 2023 - Elsevier
Rationally regulating reaction mechanisms in Fenton-like reactions by tuning the properties
of catalysts is of great significance, but still challenging. Herein, we synthesized various …

Coordination number dependent catalytic activity of single‐atom cobalt catalysts for Fenton‐like reaction

X Liang, D Wang, Z Zhao, T Li, Y Gao… - Advanced Functional …, 2022 - Wiley Online Library
Single‐atom catalysts (SACs) are widely investigated in Fenton‐like reactions for
environmental remediation, wherein their catalytic performance can be further improved by …

Identification of the electronic and structural dynamics of catalytic centers in single-Fe-atom material

X Li, CS Cao, SF Hung, YR Lu, W Cai, AI Rykov… - Chem, 2020 - cell.com
The lack of model single-atom catalysts (SACs) and atomic-resolution operando
spectroscopic techniques greatly limits our comprehension of the nature of catalysis. Herein …