Abstract The reaction of 1, 3-bis [(4-chloro) benzene] triazene (HL) and CuCl 2· 2H 2 O
affords a dinuclear triazenido–copper (II) complex [Cu 2 L 4 (NCCH 3)](1), a new molecular …

Abstract The reaction of 1-[(2-carboxyethyl) benzene]-3-[benzothiazole] triazene (HL) and
CuCl gives a trinuclear copper (I) complex,[Cu I 3 (L)(L′) 2]· THF (1· THF)(L′= the 1-[(2 …

The reaction of 2-chloroaniline and o-anisidine afforded a new triazenido ligand, 1-[(2-
methoxy) benzene]-3-[2-(chloro) benzene] triazene (HL). In the presence of Et 3 N, the …

A new molecular catalyst based on a tetra-nuclear copper (I),[Cu I 4 (L) 4] 1 is prepared by
the reaction of the triazenido ligand,[1, 3-bis (2-methoxy) benzene] triazene (HL) with CuCl …

Abstract The reaction of 1-[(2-carboxymethyl) benzene]-3-[2-pyridine] triazene (HL) with
CoCl 2· 6H 2 O affords a six-coordinated cobalt (III) complex,[CoL 3] 1, a new molecular …

The reaction of CuCl2⋅ 2H2O and a tetradentate amine phenol ligand affords a dinuclear
Cu (II) complex, 1, a new molecular electrocatalyst, whose structure has been determined by …

Abstract The reaction of 2, 3-bis (2-hydroxybenzylideneimino)-2, 3-butenedinitrile (H 2 L)
and CuCl 2· 2H 2 O affords a copper (II) complex [CuL] 1, a new molecular electrocatalyst …

Our group has developed a series of molecular electrocatalysts for hydrogen generation
based on triazenido–metal complexes (cobalt, copper, etc.). In this paper, we first present …

Abstract The reaction of 1, 3-bis [(4-chloro) benzene] triazene (HL) and [Pd (CH 3 CN) 4] Cl
2 gave a dinuclear triazenido complex Pd 2 L 4 1, which has been characterized by 1 H …

It is regarded that transition metal complexes can catalyze hydrogen production via an
unstable metal-hydride species, and the reduction reaction occurs at the metal center. In this …