[HTML][HTML] Ultrafast diffusion exchange nuclear magnetic resonance
The exchange of molecules between different physical or chemical environments due to
diffusion or chemical transformations has a crucial role in a plethora of fundamental …
diffusion or chemical transformations has a crucial role in a plethora of fundamental …
[HTML][HTML] SHARPER-DOSY: Sensitivity enhanced diffusion-ordered NMR spectroscopy
G Peat, PJ Boaler, CL Dickson, GC Lloyd-Jones… - Nature …, 2023 - nature.com
Since its discovery in mid-20th century, the sensitivity of Nuclear Magnetic Resonance
(NMR) has increased steadily, in part due to the design of new, sophisticated NMR …
(NMR) has increased steadily, in part due to the design of new, sophisticated NMR …
[HTML][HTML] Ultrafast methods for relaxation and diffusion
Relaxation and diffusion NMR measurements offer an approach to studying rotational and
translational motion of molecules non-invasively, and they also provide chemical resolution …
translational motion of molecules non-invasively, and they also provide chemical resolution …
Enhanced diffusion of molecular catalysts is due to convection
Intriguing reports of enhanced diffusion in enzymes and molecular catalysts have spurred
significant interest in experimental and theoretical investigations, and the mechanism of this …
significant interest in experimental and theoretical investigations, and the mechanism of this …
[HTML][HTML] Ultrafast transverse relaxation exchange NMR spectroscopy
Molecular exchange between different physical or chemical environments occurs due to
either diffusion or chemical transformation. Nuclear magnetic resonance (NMR) …
either diffusion or chemical transformation. Nuclear magnetic resonance (NMR) …
Matrix-assisted DOSY
IJ Day - Progress in Nuclear Magnetic Resonance …, 2020 - Elsevier
The analysis of mixtures by NMR spectroscopy is challenging. Diffusion-ordered NMR
spectroscopy enables a pseudo-separation of species based on differences in their …
spectroscopy enables a pseudo-separation of species based on differences in their …
[引用][C] Chemical exchange in diffusion NMR experiments
A Chen, CS Johnson, M Lin… - Journal of the American …, 1998 - ACS Publications
Diffusion NMR spectroscopy1 which relies on Pulse Field Gradient (PFG) NMR2 to spatially
encode molecules, enables identification and even structure determination of the individual …
encode molecules, enables identification and even structure determination of the individual …
NMR diffusion and relaxation correlation methods: New insights in heterogeneous materials
D Bernin, D Topgaard - Current opinion in colloid & interface science, 2013 - Elsevier
Heterogeneous materials, such as biological tissues, foodstuffs, and rocks, contain a range
of microscopic environments where the molecular constituents often have different NMR …
of microscopic environments where the molecular constituents often have different NMR …
[HTML][HTML] Suppressing exchange effects in diffusion-ordered NMR spectroscopy
In diffusion-ordered spectroscopy (DOSY) the aim is to separate signals from different
molecular species according to their different diffusion coefficients. Each species has its …
molecular species according to their different diffusion coefficients. Each species has its …
High-Resolution Diffusion and Relaxation Edited One- and Two-Dimensional 1H NMR Spectroscopy of Biological Fluids
M Liu, JK Nicholson, JC Lindon - Analytical Chemistry, 1996 - ACS Publications
A new approach to the characterization of biomolecules in whole biological fluids is
presented based on simplification of 1H NMR spectra by utilizing differences in molecular …
presented based on simplification of 1H NMR spectra by utilizing differences in molecular …