Highly acidic ambient particles, soluble metals, and oxidative potential: a link between sulfate and aerosol toxicity

T Fang, H Guo, L Zeng, V Verma… - … science & technology, 2017 - ACS Publications
Soluble transition metals in particulate matter (PM) can generate reactive oxygen species in
vivo by redox cycling, leading to oxidative stress and adverse health effects. Most metals …

Evaluating the health risk from secondary sulfates in eastern North American regional ambient air particulate matter

TJ Grahame, RB Schlesinger - Inhalation toxicology, 2005 - Taylor & Francis
Epidemiological studies of particulate matter (PM) using central area monitors have
associated total PM mass, as well as certain individual components of PM, including sulfate …

Enhanced rates of transition-metal-ion-catalyzed oxidation of S (IV) in aqueous aerosols: Insights into sulfate aerosol formation in the atmosphere

KJ Angle, EE Neal, VH Grassian - Environmental Science & …, 2021 - ACS Publications
The oxidation of S (IV) is a critical step in the fate of sulfur dioxide emissions that determines
the amount of sulfate aerosol in the atmosphere. Herein, we measured accelerated S (IV) …

PM water-soluble elements in the southeastern United States: automated analytical method development, spatiotemporal distributions, source apportionment, and …

T Fang, H Guo, V Verma, RE Peltier… - … Chemistry and Physics, 2015 - acp.copernicus.org
Water-soluble redox-active metals are potentially toxic due to its ability to catalytically
generate reactive oxygen species (ROS) in vivo, leading to oxidative stress. As part of the …

[HTML][HTML] Aerosol high water contents favor sulfate and secondary organic aerosol formation from fossil fuel combustion emissions

X Huang, Z Liu, Y Ge, Q Li, X Wang, H Fu… - npj Climate and …, 2023 - nature.com
Fine-particle pollution associated with high sulfate and secondary organic aerosol (SOA)
contents still occurs in winter, despite considerable reductions in precursor emissions in …

[HTML][HTML] High levels of ammonia do not raise fine particle pH sufficiently to yield nitrogen oxide-dominated sulfate production

H Guo, RJ Weber, A Nenes - Scientific Reports, 2017 - nature.com
High levels of ammonia (NH3) have been suggested to elevate ambient particle pH levels to
near neutral acidity (pH= 7), a condition that promotes rapid SO2 oxidation by NO2 to form …

[HTML][HTML] Significant formation of sulfate aerosols contributed by the heterogeneous drivers of dust surface

T Wang, Y Liu, H Cheng, Z Wang, H Fu… - Atmospheric …, 2022 - acp.copernicus.org
The importance of dust heterogeneous oxidation in the removal of atmospheric SO 2 and
formation of sulfate aerosols is not adequately understood. In this study, the Fe-, Ti-, and Al …

Evidence of health impacts of sulfate-and nitrate-containing particles in ambient air

R Reiss, EL Anderson, CE Cross, G Hidy… - Inhalation …, 2007 - Taylor & Francis
Ambient particulate matter (PM) is a complex mixture of inorganic and organic compounds.
The US Environmental Protection Agency (EPA) regulates PM as a criteria pollutant and …

[HTML][HTML] Insights into elemental composition and sources of fine and coarse particulate matter in dense traffic areas in Toronto and Vancouver, Canada

V Celo, MM Yassine, E Dabek-Zlotorzynska - Toxics, 2021 - mdpi.com
Traffic is a significant pollution source in cities and has caused various health and
environmental concerns worldwide. Therefore, an improved understanding of traffic impacts …

Fast oxidation of sulfur dioxide by hydrogen peroxide in deliquesced aerosol particles

T Liu, SL Clegg, JPD Abbatt - Proceedings of the National …, 2020 - National Acad Sciences
Atmospheric sulfate aerosols have important impacts on air quality, climate, and human and
ecosystem health. However, current air-quality models generally underestimate the rate of …