Highly acidic ambient particles, soluble metals, and oxidative potential: a link between sulfate and aerosol toxicity
Soluble transition metals in particulate matter (PM) can generate reactive oxygen species in
vivo by redox cycling, leading to oxidative stress and adverse health effects. Most metals …
vivo by redox cycling, leading to oxidative stress and adverse health effects. Most metals …
Evaluating the health risk from secondary sulfates in eastern North American regional ambient air particulate matter
TJ Grahame, RB Schlesinger - Inhalation toxicology, 2005 - Taylor & Francis
Epidemiological studies of particulate matter (PM) using central area monitors have
associated total PM mass, as well as certain individual components of PM, including sulfate …
associated total PM mass, as well as certain individual components of PM, including sulfate …
Enhanced rates of transition-metal-ion-catalyzed oxidation of S (IV) in aqueous aerosols: Insights into sulfate aerosol formation in the atmosphere
KJ Angle, EE Neal, VH Grassian - Environmental Science & …, 2021 - ACS Publications
The oxidation of S (IV) is a critical step in the fate of sulfur dioxide emissions that determines
the amount of sulfate aerosol in the atmosphere. Herein, we measured accelerated S (IV) …
the amount of sulfate aerosol in the atmosphere. Herein, we measured accelerated S (IV) …
PM water-soluble elements in the southeastern United States: automated analytical method development, spatiotemporal distributions, source apportionment, and …
Water-soluble redox-active metals are potentially toxic due to its ability to catalytically
generate reactive oxygen species (ROS) in vivo, leading to oxidative stress. As part of the …
generate reactive oxygen species (ROS) in vivo, leading to oxidative stress. As part of the …
[HTML][HTML] Aerosol high water contents favor sulfate and secondary organic aerosol formation from fossil fuel combustion emissions
Fine-particle pollution associated with high sulfate and secondary organic aerosol (SOA)
contents still occurs in winter, despite considerable reductions in precursor emissions in …
contents still occurs in winter, despite considerable reductions in precursor emissions in …
[HTML][HTML] High levels of ammonia do not raise fine particle pH sufficiently to yield nitrogen oxide-dominated sulfate production
High levels of ammonia (NH3) have been suggested to elevate ambient particle pH levels to
near neutral acidity (pH= 7), a condition that promotes rapid SO2 oxidation by NO2 to form …
near neutral acidity (pH= 7), a condition that promotes rapid SO2 oxidation by NO2 to form …
[HTML][HTML] Significant formation of sulfate aerosols contributed by the heterogeneous drivers of dust surface
The importance of dust heterogeneous oxidation in the removal of atmospheric SO 2 and
formation of sulfate aerosols is not adequately understood. In this study, the Fe-, Ti-, and Al …
formation of sulfate aerosols is not adequately understood. In this study, the Fe-, Ti-, and Al …
Evidence of health impacts of sulfate-and nitrate-containing particles in ambient air
R Reiss, EL Anderson, CE Cross, G Hidy… - Inhalation …, 2007 - Taylor & Francis
Ambient particulate matter (PM) is a complex mixture of inorganic and organic compounds.
The US Environmental Protection Agency (EPA) regulates PM as a criteria pollutant and …
The US Environmental Protection Agency (EPA) regulates PM as a criteria pollutant and …
[HTML][HTML] Insights into elemental composition and sources of fine and coarse particulate matter in dense traffic areas in Toronto and Vancouver, Canada
V Celo, MM Yassine, E Dabek-Zlotorzynska - Toxics, 2021 - mdpi.com
Traffic is a significant pollution source in cities and has caused various health and
environmental concerns worldwide. Therefore, an improved understanding of traffic impacts …
environmental concerns worldwide. Therefore, an improved understanding of traffic impacts …
Fast oxidation of sulfur dioxide by hydrogen peroxide in deliquesced aerosol particles
Atmospheric sulfate aerosols have important impacts on air quality, climate, and human and
ecosystem health. However, current air-quality models generally underestimate the rate of …
ecosystem health. However, current air-quality models generally underestimate the rate of …
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