Ring-opening copolymerization of maleic anhydride with epoxides: a chain-growth approach to unsaturated polyesters

AM DiCiccio, GW Coates - Journal of the American Chemical …, 2011 - ACS Publications
We report the ring-opening copolymerization of maleic anhydride with a variety of epoxides
catalyzed by a chromium (III) salen complex. Quantitative isomerization of the cis-maleate …

Development of highly active and regioselective catalysts for the copolymerization of epoxides with cyclic anhydrides: an unanticipated effect of electronic variation

AM DiCiccio, JM Longo… - Journal of the …, 2016 - ACS Publications
Recent developments in polyester synthesis have established several systems based on
zinc, chromium, cobalt, and aluminum catalysts for the ring-opening alternating …

Alternating copolymerization of propylene oxide with biorenewable terpene‐based cyclic anhydrides: a sustainable route to aliphatic polyesters with high glass …

NJ Van Zee, GW Coates - Angewandte Chemie, 2015 - Wiley Online Library
The alternating copolymerization of propylene oxide with terpene‐based cyclic anhydrides
catalyzed by chromium, cobalt, and aluminum salen complexes is reported. The use of the …

Mechanism-inspired design of bifunctional catalysts for the alternating ring-opening copolymerization of epoxides and cyclic anhydrides

BA Abel, CAL Lidston, GW Coates - Journal of the American …, 2019 - ACS Publications
Advances in catalysis have enabled the ring-opening copolymerization of epoxides and
cyclic anhydrides to afford structurally and functionally diverse polyesters with controlled …

Electronic effects of aluminum complexes in the copolymerization of propylene oxide with tricyclic anhydrides: access to well-defined, functionalizable aliphatic …

NJ Van Zee, MJ Sanford… - Journal of the American …, 2016 - ACS Publications
The synthesis of well-defined and functionalizable aliphatic polyesters remains a key
challenge in the advancement of emerging drug delivery and self-assembly technologies …

Binuclear chromium–salan complex catalyzed alternating copolymerization of epoxides and cyclic anhydrides

J Liu, YY Bao, Y Liu, WM Ren, XB Lu - Polymer Chemistry, 2013 - pubs.rsc.org
Mono-and bi-nuclear chromium (III)–salan complexes are efficient catalysts for the
alternating copolymerization of terminal epoxides [such as epichlorohydrin (ClPO) and …

Alternating copolymerization of epoxides and cyclic anhydrides: an improved route to aliphatic polyesters

RC Jeske, AM DiCiccio, GW Coates - Journal of the American …, 2007 - ACS Publications
Beta-diiminate zinc catalysts are reported for the synthesis of aliphatic polyesters via the
highly alternating copolymerization of epoxides and cyclic anhydrides under mild reaction …

Highly active organic lewis pairs for the copolymerization of epoxides with cyclic anhydrides: metal-free access to well-defined aliphatic polyesters

LF Hu, CJ Zhang, HL Wu, JL Yang, B Liu… - …, 2018 - ACS Publications
Polyester synthesis from the alternating copolymerization of epoxides with cyclic anhydrides
via a metal-free route remains a key challenge. This work reports the development of a …

Ring-opening copolymerization of epoxides and cyclic anhydrides with discrete metal complexes: structure–property relationships

JM Longo, MJ Sanford, GW Coates - Chemical reviews, 2016 - ACS Publications
Polyesters synthesized through the alternating copolymerization of epoxides and cyclic
anhydrides compose a growing class of polymers that exhibit an impressive array of …

Hydrophilic aliphatic polyesters: design, synthesis, and ring-opening polymerization of functional cyclic esters

M Trollsås, VY Lee, D Mecerreyes… - …, 2000 - ACS Publications
The synthesis and homo-and copolymerization of new cyclic esters containing protected
functional groups (hydroxyl, bishydroxyl, amino, and carboxyl) are described. Each of the ε …