[HTML][HTML] Impact of lignin source on the performance of thermoset resins

I Ribca, B Sochor, M Betker, SV Roth, M Lawoko… - European Polymer …, 2023 - Elsevier
A series of different technical hardwood lignin-based resins have been successfully
synthesized, characterized, and utilised to produce thiol-ene thermoset polymers. Firstly …

Effect of Molecular Organization on the Properties of Fractionated Lignin-Based Thiol–Ene Thermoset Materials

I Ribca, B Sochor, SV Roth, M Lawoko, MAR Meier… - Acs Omega, 2023 - ACS Publications
In this study, the combination of sequential solvent fractionation of technical Kraft lignin was
followed by allylation of most OH functionalities to give highly functional thermoset resins. All …

Renewable thiol–ene thermosets based on refined and selectively allylated industrial lignin

M Jawerth, M Johansson, S Lundmark… - ACS Sustainable …, 2017 - ACS Publications
Aromatic material constituents derived from renewable resources are attractive for new
biobased polymer systems. Lignin, derived from lignocellulosic biomass, is the most …

Reactivity enhancement of organosolv lignin by phenolation for improved bio-based thermosets

J Podschun, B Saake, R Lehnen - European Polymer Journal, 2015 - Elsevier
Lignin can function as a structural backbone in a variety of resin systems such as phenol
formaldehyde, epoxy and polybenzoxazine. However, the low number of reactive sites …

Exploring the effects of different cross-linkers on lignin-based thermoset properties and morphologies

I Ribca, ME Jawerth, CJ Brett, M Lawoko… - ACS Sustainable …, 2021 - ACS Publications
The search for sustainable material solutions has put lignin as one of the prime candidates
for aromatic building blocks in macromolecular materials. The present study aimed to …

Mechanical and morphological properties of lignin-based thermosets

ME Jawerth, CJ Brett, C Terrier… - ACS Applied Polymer …, 2020 - ACS Publications
The need for renewable alternatives for fossil-based aromatic material constituents is
evident for a more sustainable society. Lignin is the largest source of naturally occurring …

Tunable thermosetting epoxies based on fractionated and well-characterized lignins

C Gioia, G Lo Re, M Lawoko… - Journal of the American …, 2018 - ACS Publications
Here we report the synthesis of thermosetting resins from low molar mass Kraft lignin
fractions of high functionality, refined by solvent extraction. Such fractions were fully …

Allylation of a lignin model phenol: a highly selective reaction under benign conditions towards a new thermoset resin platform

M Jawerth, M Lawoko, S Lundmark… - RSC …, 2016 - pubs.rsc.org
The lack of aromatic material constituents derived from renewable resources poses a
problem to meet the future demands of a more sustainable society. Lignin is the most …

Lignin reinforcement in thermosets composites

G Engelmann, J Ganster - 2016 - publica.fraunhofer.de
With its highly branched structure, its functional groups, and its free ring positions in the
aromatic monomers, lignin is a promising bio-based candidate for network formation in resin …

Epoxy thermosets from model mixtures of the lignin-to-vanillin process

M Fache, B Boutevin, S Caillol - Green Chemistry, 2016 - pubs.rsc.org
Epoxy thermosets were prepared from mixtures of phenolics modelling the product stream of
the lignin-to-vanillin process. Vanillin is one of the only mono-aromatic compounds …