The choice of backbone linker for two ortho-bis-(9-borafluorene) s has a great influence on
the LUMO located at the boron centers and, therefore, the reactivity of the respective …

The synthesis of [1, 1′-bis (o-carboranyl)] boranes was achieved through the deprotonation
of 1, 1′-bis (o-carborane) reagents followed by salt metathesis with (iPr) 2NBCl2. X-ray …

Abstract Formation of borabicyclo [3.2. 0] heptadiene derivatives was achieved via boron‐
insertion into aromatic C− C bonds in the photo‐promoted skeletal rearrangement reaction …

The targeted hydrolysis of the 9, 10‐dihydro‐9, 10‐diboraanthracene adduct (Me2S) HB
(C6H4) 2BH (SMe2)(1) with 0.5 equiv of H2O leads to formation of the borinic acid …

The synthesis of 9-borafluorene with an electron-withdrawing o-carboranyl substituent and
its reactions with a series of alkenes are described. The o-carboranyl substituent is bonded …

Direct insertion of unsaturated substrates into a five‐membered borole ring is a useful
method to obtain valuable heterocycles containing one or more three‐coordinate boron …

Carborynes (1, 2-dehydro-o-carborane and 1, 3-dehydro-o-carborane), three-dimensional
analogues of benzyne, can be generated in situ from the precursors 1-X-2-Li-1, 2 …

Organoboranes are among the most versatile and widely used reagents in synthetic
chemistry. A significant further expansion of their application spectrum would be achievable …

A series of naphthyl-bridged amino-borane derivatives, namely 1-(dimethylamino)-8-
naphthylboranes (1, 3, 5, 7) and 5-(dimethylamino)-6-acenaphthylboranes (2, 4, 6, 8, 10 …

The addition of 2 eq. of MesLi to the biphenylene-containing 9, 10-dihydro-9, 10-
diboraanthracene (DBA) 2 results in the formation of the corresponding …