Mesoionic and related less heteroatom-stabilized N-heterocyclic carbene complexes: synthesis, catalysis, and other applications
A Vivancos, C Segarra, M Albrecht - Chemical reviews, 2018 - ACS Publications
Mesoionic carbenes are a subclass of the family of N-heterocyclic carbenes that generally
feature less heteroatom stabilization of the carbenic carbon and hence impart specific donor …
feature less heteroatom stabilization of the carbenic carbon and hence impart specific donor …
A brief survey of our contribution to stable carbene chemistry
D Martin, M Melaimi, M Soleilhavoup… - Organometallics, 2011 - ACS Publications
This personal account summarizes our work, beginning with the discovery of the first stable
carbene in 1988 up until the recent isolation of mesoionic carbenes. It explains why we have …
carbene in 1988 up until the recent isolation of mesoionic carbenes. It explains why we have …
[引用][C] Stability and Electronic Properties of Imidazole‐Based Mesoionic Carbenes
G Ung, G Bertrand - Chemistry–A European Journal, 2011 - Wiley Online Library
During the last two decades, stable carbenes,[1, 2] especially N-heterocyclic carbenes
(NHCs)(A), have been widely used as ligand for transition-metal complexes.[3] Among their …
(NHCs)(A), have been widely used as ligand for transition-metal complexes.[3] Among their …
Abnormal, mesoionic and remote N-heterocyclic carbene complexes
RH Crabtree - Coordination Chemistry Reviews, 2013 - Elsevier
Three different structural classes of NHC ligands can be distinguished: normal (nNHC),
abnormal (aNHC), alternatively called mesoionic (MIC), and remote (rNHC). General …
abnormal (aNHC), alternatively called mesoionic (MIC), and remote (rNHC). General …
[图书][B] Contemporary carbene chemistry
RA Moss, MP Doyle - 2013 - books.google.com
Presents the most innovative results in carbene chemistry, setting the foundation for new
discoveries and applications The discovery of stable carbenes has reinvigorated carbene …
discoveries and applications The discovery of stable carbenes has reinvigorated carbene …
Recent advances in the chemistry and applications of N-heterocyclic carbenes
N-Heterocyclic carbenes, despite being isolated and characterized three decades ago, still
capture scientists' interest as versatile, modular and strongly coordinating moieties. In the …
capture scientists' interest as versatile, modular and strongly coordinating moieties. In the …
Anionic N-heterocyclic carbenes: Synthesis, coordination chemistry and applications in homogeneous catalysis
A Nasr, A Winkler, M Tamm - Coordination Chemistry Reviews, 2016 - Elsevier
N-Heterocyclic carbenes (NHCs) are nowadays ubiquitous and indispensable as ancillary
ligands in organotransition metal chemistry, with an enormous variety of NHC types known …
ligands in organotransition metal chemistry, with an enormous variety of NHC types known …
Anionic tethered N-heterocyclic carbene chemistry
ST Liddle, IS Edworthy, PL Arnold - Chemical Society Reviews, 2007 - pubs.rsc.org
Since the discovery of a stable “bottleable” N-heterocyclic carbene (NHC), there has been a
spectacular explosion of interest in this ligand class. This interest stems from a desire to …
spectacular explosion of interest in this ligand class. This interest stems from a desire to …
N,N′-Diamidocarbenes: Isolable Divalent Carbons with Bona Fide Carbene Reactivity
JP Moerdyk, D Schilter… - Accounts of Chemical …, 2016 - ACS Publications
Conspectus Since the first reported isolation of a carbene just over a quarter century ago,
the study of such compounds including stable derivatives has flourished. Indeed, N …
the study of such compounds including stable derivatives has flourished. Indeed, N …
1H-1,2,3-Triazol-5-ylidenes: Readily Available Mesoionic Carbenes
G Guisado-Barrios, M Soleilhavoup… - Accounts of Chemical …, 2018 - ACS Publications
Conspectus Classical carbenes are usually described as neutral compounds featuring a
divalent carbon with only six electrons in their valence shell. It was only in 1988 that our …
divalent carbon with only six electrons in their valence shell. It was only in 1988 that our …