A spatially orthogonal hierarchically porous acid–base catalyst for cascade and antagonistic reactions
Complex organic molecules are of great importance to research and industrial chemistry
and typically synthesized from smaller building blocks by multistep reactions. The ability to …
and typically synthesized from smaller building blocks by multistep reactions. The ability to …
Gradient hierarchically porous structure for rapid capillary-assisted catalysis
Synthesis of hierarchically porous structures with uniform spatial gradient and structure
reinforcement effect still remains a great challenge. Herein, we report the synthesis of …
reinforcement effect still remains a great challenge. Herein, we report the synthesis of …
Unravelling mass transport in hierarchically porous catalysts
MA Isaacs, N Robinson, B Barbero… - Journal of Materials …, 2019 - pubs.rsc.org
Bio-derived platform chemicals and fuels are important for the development of sustainable
manufacturing. However, their efficient production from biomass necessitates new catalysts …
manufacturing. However, their efficient production from biomass necessitates new catalysts …
Spatially orthogonal chemical functionalization of a hierarchical pore network for catalytic cascade reactions
The chemical functionality within porous architectures dictates their performance as
heterogeneous catalysts; however, synthetic routes to control the spatial distribution of …
heterogeneous catalysts; however, synthetic routes to control the spatial distribution of …
Synthesis of solid catalysts with spatially resolved acidic and basic molecular functionalities
Z Weng, T Yu, F Zaera - Acs Catalysis, 2018 - ACS Publications
A synthetic procedure was developed to prepare dual acid–base catalysts on a single
platform. Mesoporous SBA-15 was derivatized using known grafting chemistry via the …
platform. Mesoporous SBA-15 was derivatized using known grafting chemistry via the …
Reaction design for the compartmented combination of heterogeneous and enzyme catalysis
JM Sperl, JM Carsten, JK Guterl, P Lommes… - ACS …, 2016 - ACS Publications
The combination of a heterogeneously catalyzed reaction with a biotransformation as a one-
pot cascade process is an important strategy to reduce costs, time, and labor efforts in the …
pot cascade process is an important strategy to reduce costs, time, and labor efforts in the …
A trifunctional mesoporous silica-based, highly active catalyst for one-pot, three-step cascade reactions
We report the synthesis of a trifunctional catalyst containing amine, sulphonic acid and Pd
nanoparticle catalytic groups anchored on the pore walls of SBA-15. The catalyst efficiently …
nanoparticle catalytic groups anchored on the pore walls of SBA-15. The catalyst efficiently …
A bifunctional zeolitic porous liquid with incompatible Lewis pairs for antagonistic cascade catalysis
The emergence of porous liquids (PLs) opened opportunities to form unique antagonistic
systems capable of fulfilling cascade reactions promoted by incompatible active sites in one …
systems capable of fulfilling cascade reactions promoted by incompatible active sites in one …
[HTML][HTML] Mesoporous silica with site-isolated amine and phosphotungstic acid groups: a solid catalyst with tunable antagonistic functions for one-pot tandem reactions
Scientists engaged in heterogeneous catalysis often cite enzymes as their model catalysts.
Enzymes can efficiently catalyze multistep processes that give various types of …
Enzymes can efficiently catalyze multistep processes that give various types of …
A porous Brønsted superacid as an efficient and durable solid catalyst
The development of catalysts able to assist industrial chemical transformations is a topic of
high importance. In view of the versatile catalytic capabilities of acid catalysts, extensive …
high importance. In view of the versatile catalytic capabilities of acid catalysts, extensive …