Theory of core-level spectroscopy of rare-earth oxides

A Kotani, H Ogasawara - Journal of electron spectroscopy and related …, 1992 - Elsevier
A review is presented of the recent development in theoretical studies of X-ray
photoemission spectra (XPS) and X-ray absorption spectra (XAS) for rare-earth …

Theory of x-ray-absorption spectra in and some other rare-earth compounds

H Ogasawara, A Kotani, K Okada, BT Thole - Physical Review B, 1991 - APS
We analyze rare-earth 3d-core x-ray-absorption spectra (3d XAS) in PrO 2, as well as in
CeO 2, using the impurity Anderson model. It is shown that the interplay between the atomic …

Effect of valence mixing on multiplet structure in core photoabsorption spectra for Ce compounds

T Jo, A Kotani - Physical Review B, 1988 - APS
The effect of valence mixing on multiplet structure in the Ce 4 d x-ray absorption spectra for
Ce Rh 3 and Ce O 2 is discussed on the basis of a simplified impurity Anderson model …

Relationships between complex core level spectra and materials properties

CJ Nelin, PS Bagus, ES Ilton… - … Journal of Quantum …, 2010 - Wiley Online Library
The XPS of many oxides are quite complex and there may be several peaks of significant
intensity for each subshell. These peaks arise from many‐electron effects, which normally …

X-ray photoelectron spectroscopy of rare-earth compounds

Y Uwamino, T Ishizuka, H Yamatera - Journal of Electron Spectroscopy and …, 1984 - Elsevier
A variety of rare-earth (RE) compounds (oxides, sulfates and oxalates) have been studied by
X-ray photoelectron spectroscopy. Except for Eu, the binding energies (BE's) of the RE 3d …

Optical study on electronic structure of rare-earth sesquioxides

S Kimura, F Arai, M Ikezawa - Journal of the Physical Society of …, 2000 - journals.jps.jp
Reflectivity spectra of nine rare-earth sesquioxide (R 2 O 3; R= La, Pr, Nd, Sm, Eu, Er, Tm,
Yb and Lu) single crystals have been measured in the photon energy range from 0.5 to 50 …

Transition Probabilities and Overlap-Covalency Effects in the X-Ray Photoemission Spectra of Transition-Metal Compounds:

GK Wertheim, LF Mattheiss, M Campagna… - Physical Review Letters, 1974 - APS
Differences in photoelectric transition probabilities have an important effect on the
interpretation of x-ray photoemission spectra of transition-metal compounds with …

X-ray absorption study of the ZrO2 Y2O3 system

MH Tuilier, J Dexpert-Ghys, H Dexpert… - Journal of Solid State …, 1987 - Elsevier
A complete EXAFS analysis of the ZrO 2 Y 2 O 3 system has been performed at both the
yttrium and zirconium K absorption edges. The main result of this work is that the first …

The electronic structure of rare-earth oxides in the creation of the core hole

C Suzuki, J Kawai, M Takahashi, AM Vlaicu, H Adachi… - Chemical Physics, 2000 - Elsevier
We studied the electronic structures of rare-earth sesqui-oxides R2O3 (R: rare-earth
element) with a core hole, both experimentally and theoretically. The experimental study …

X-ray absorption studies of , , and . II. Rare-earth valence state by absorption edges

H Dexpert, RC Karnatak, JM Esteva, JP Connerade… - Physical Review B, 1987 - APS
The L III absorption edges of fluorite-structure-related CeO 2, PrO 2, and TbO 2 show four
well-resolved spectral features. The systematic trend in their positions and relative …