During the past decade we have witnessed the rapid development and understanding of
living radical polymerization (LRP)(or reversible deactivation radical polymerizations …

The discovery of the first “living” radical polymerization by Otsu and co-workers (1) in 1982
heralded the start of a very exciting time for polymer chemists. Since then, a plethora of living …

Cu (0)-mediated living radical polymerization or single electron transfer living radical
polymerization (Cu (0)-mediated LRP or SET-LRP) is a versatile polymerization technique …

Two picolyl structure based amines, the tridentate N, N-bis (2-pyridylmethyl) octylamine
(BPMOA) and the tetradentate tris [(2-pyridyl) methyl] amine, have been successfully …

As a method for overcoming the challenge of rigorous deoxygenation in copper‐mediated
controlled radical polymerization processes [eg, atom‐transfer radical polymerization …

Cu (0) was prepared via disproportionation of Cu (I) Br in the presence of Me6‐TREN in
various solvents in a glove box. The resulting nanopowders were used as mimics of …

Over the past few decades, controlled/living polymerization methodology has steadily
expanded to include all of the chain-growth polymerization methods: cationic, anionic …

Several propositions have been made about the mechanism in which Cu0 mediates
controlled radical polymerization that include (1) exclusive activation of an alkyl halide …

Conventional metal-catalyzed organic radical reactions and living radical polymerizations
(LRP) performed in nonpolar solvents, including atom-transfer radical polymerization …

Abstract Single Electron Transfer‐Living Radical Polymerization (SET‐LRP) represents a
robust and versatile method for the rapid synthesis of macromolecules with well defined …