Diethylboryl‐2, 3′‐bipyridine (1), which is inaccessible by conventional batch methods,
was synthesized by using a flow microreactor. Compound 1 was obtained as an equilibrium …

The self-assembly of 3-[4 '-(diethylboryl) phenyl] pyridine (3) and 3-[3 '-(diethylboryl) phenyl]
pyridine (4) was investigated by 1H and 11B NMR spectroscopies and vapor pressure …

A facile method for the synthesis of 3-(dimethylboryl) pyridine (1a) is described. Compound
1a assembles into a rigid cyclic tetramer stabilized via intermolecular boron− nitrogen …

Herein we report that 4-pyridinylboronic acid (1) in the solid state self-assembles into
tetrameric macrocycles via B–N bond formation. The tetramers are linked via O–H··· O bonds …

Abstract The synthesis of 5, 5′-dibromo-2, 2′-bipyridine and 5-bromo-2, 2′-bipyridine,
useful intermediates for elaboration into more complex ligands through metal-catalyzed …

In a flow microreactor, aryllithiums bearing a piperidylmethyl group were generated using
nBuLi by precise residence time control and effective temperature control, and then …

The solution phase self-assembly of boronate esters, diazaboroles, oxathiaboroles, and
dithiaboroles from the condensation of arylboronic acids with aromatic diol, diamine …

Supramolecular polymerization in the family of benzene-1, 3, 5-tricarboxamide (BTA) has
been investigated using atomistic molecular dynamics (MD) simulations. Gas phase …

A combination of flow and batch chemistries has been successfully applied to the assembly
of a series of trisubstituted drug-like pyrrolidines. This study demonstrates the efficient …

Designing the reactant molecule of an initial reaction, based on quantum chemical pathway
exploration, enabled us to access a new reaction, ie, the tetraborylation reaction of p …