Slow Magnetic Relaxation in Trigonal-Planar Mononuclear Fe (II) and Co (II) Bis (trimethylsilyl) amido Complexes A Comparative Study
A Eichhöfer, Y Lan, V Mereacre… - Inorganic …, 2014 - ACS Publications
Alternating current magnetic investigations on the trigonal-planar high-spin Co2+ complexes
[Li (15-crown-5)][Co {N (SiMe3) 2} 3],[Co {N (SiMe3) 2} 2 (THF)](THF= tetrahydrofuran), and …
[Li (15-crown-5)][Co {N (SiMe3) 2} 3],[Co {N (SiMe3) 2} 2 (THF)](THF= tetrahydrofuran), and …
Mössbauer Spectroscopy as a Probe of Magnetization Dynamics in the Linear Iron(I) and Iron(II) Complexes [Fe(C(SiMe3)3)2]1–/0
The iron-57 Mössbauer spectra of the linear, two-coordinate complexes,[K (crypt-222)][Fe
(C (SiMe3) 3) 2], 1, and Fe (C (SiMe3) 3) 2, 2, were measured between 5 and 295 K under …
(C (SiMe3) 3) 2], 1, and Fe (C (SiMe3) 3) 2, 2, were measured between 5 and 295 K under …
Slow Magnetic Relaxation in Intermediate Spin S = 3/2 Mononuclear Fe(III) Complexes
Magneto-structural correlation studies of mononuclear intermediate S= 3/2 Fe (III)
complexes,(PMe3) 2FeCl3 (1) and (PMe2Ph) 2FeCl3 (2), demonstrate the influence of local …
complexes,(PMe3) 2FeCl3 (1) and (PMe2Ph) 2FeCl3 (2), demonstrate the influence of local …
Slow magnetic relaxation in a series of mononuclear 8-coordinate Fe (II) and Co (II) complexes
XX Jin, XX Chen, J Xiang, YZ Chen, LH Jia… - Inorganic …, 2018 - ACS Publications
A series of homoleptic mononuclear 8-coordinate FeII and CoII compounds,[FeII (L 2)
2](ClO4) 2 (2),[FeII (L 3) 2](ClO4) 2 (3),[FeII (L 4) 2](ClO4) 2 (4),[CoII (L 1) 2](ClO4) 2 (5),[CoII …
2](ClO4) 2 (2),[FeII (L 3) 2](ClO4) 2 (3),[FeII (L 4) 2](ClO4) 2 (4),[CoII (L 1) 2](ClO4) 2 (5),[CoII …
Field-Induced Slow Magnetic Relaxation in the Ni(I) Complexes [NiCl(PPh3)2]·C4H8O and [Ni(N(SiMe3)2)(PPh3)2]
W Lin, T Bodenstein, V Mereacre, K Fink… - Inorganic …, 2016 - ACS Publications
Direct current (dc) and alternating current (ac) magnetic measurements have been
performed on the three Ni (I) complexes:[NiCl (PPh3) 3],[NiCl (PPh3) 2]· C4H8O, and [Ni (N …
performed on the three Ni (I) complexes:[NiCl (PPh3) 3],[NiCl (PPh3) 2]· C4H8O, and [Ni (N …
Importance of Out-of-State Spin–Orbit Coupling for Slow Magnetic Relaxation in Mononuclear FeII Complexes
PH Lin, NC Smythe, SI Gorelsky… - Journal of the …, 2011 - ACS Publications
Two mononuclear high-spin FeII complexes with trigonal planar ([FeII (N (TMS) 2) 2
(PCy3)](1) and distorted tetrahedral ([FeII (N (TMS) 2) 2 (depe)](2) geometries are reported …
(PCy3)](1) and distorted tetrahedral ([FeII (N (TMS) 2) 2 (depe)](2) geometries are reported …
Insights into single-molecule-magnet behavior from the experimental electron density of linear two-coordinate iron complexes
MK Thomsen, A Nyvang, JPS Walsh… - Inorganic …, 2019 - ACS Publications
A breakthrough in the study of single-molecule magnets occurred with the discovery of zero-
field slow magnetic relaxation and hysteresis for the linear iron (I) complex [Fe (C (SiMe3) 3) …
field slow magnetic relaxation and hysteresis for the linear iron (I) complex [Fe (C (SiMe3) 3) …
Slow magnetic relaxation in a family of trigonal pyramidal iron (II) pyrrolide complexes
We present a family of trigonal pyramidal iron (II) complexes supported by tris (pyrrolyl-α-
methyl) amine ligands of the general formula [M (solv) n][(tpaR) Fe](M= Na, R= tert-butyl (1) …
methyl) amine ligands of the general formula [M (solv) n][(tpaR) Fe](M= Na, R= tert-butyl (1) …
Slow relaxation of magnetization in a bis-mer-tridentate octahedral Co (II) complex
Reaction of a rigid tridentate ligand o-[(1H-imidazol-2-yl) methylideneamino] phenol (2-
H2imap) with Co (ClO4) 2 in the presence of NaN3, or Co (NO3) 2 without a base yields …
H2imap) with Co (ClO4) 2 in the presence of NaN3, or Co (NO3) 2 without a base yields …
Heterometallic 3d–4f single-molecule magnets: ligand and metal ion influences on the magnetic relaxation
SK Langley, C Le, L Ungur, B Moubaraki… - Inorganic …, 2015 - ACS Publications
Six tetranuclear 3d–4f single-molecule magnet (SMM) complexes formed using Nn-
butyldiethanolamine and N-methyldiethanolamine in conjunction with ortho-and para …
butyldiethanolamine and N-methyldiethanolamine in conjunction with ortho-and para …