Aerobic cleavage of alkenes and alkynes into carbonyl and carboxyl compounds
G Urgoitia, R SanMartin, MT Herrero… - ACS Catalysis, 2017 - ACS Publications
This review provides an overview of the recent developments on the oxygen-mediated
cleavage of olefins and acetylene derivatives to provide carbonyl and carboxylic …
cleavage of olefins and acetylene derivatives to provide carbonyl and carboxylic …
Aerobic oxidative cleavage and esterification of C (OH)–C bonds
Summary C (OH)–C bonds are widely distributed in naturally renewable biomass, such as
carbohydrates, lignin, and their platform molecules. Selective cleavage and functionalization …
carbohydrates, lignin, and their platform molecules. Selective cleavage and functionalization …
Catalytic, mild, and selective oxyfunctionalization of linear alkanes: current challenges
M Bordeaux, A Galarneau… - Angewandte Chemie …, 2012 - Wiley Online Library
Selective catalysts for sustainable oxidation of alkanes are highly demanded because of the
abundance of these molecules in the environment, the possibility to transform them into …
abundance of these molecules in the environment, the possibility to transform them into …
Oxidative alkene cleavage by chemical and enzymatic methods
A Rajagopalan, M Lara, W Kroutil - Advanced Synthesis & …, 2013 - Wiley Online Library
The cleavage of alkenes to the corresponding carbonyl products is a widely employed
method in organic synthesis, especially to introduce oxygen functionalities into molecules …
method in organic synthesis, especially to introduce oxygen functionalities into molecules …
Transition metal-catalyzed oxidative double bond cleavage of simple and bio-derived alkenes and unsaturated fatty acids
P Spannring, PCA Bruijnincx… - Catalysis Science & …, 2014 - pubs.rsc.org
The oxidative cleavage of the CC double bond in unsaturated fatty acids into aldehydes or
carboxylic acids is a reaction of current interest in biomass valorization. The products of this …
carboxylic acids is a reaction of current interest in biomass valorization. The products of this …
Development of High Performance Heterogeneous Catalysts for Selective Cleavage of C− O and C− C Bonds of Biomass‐Derived Oxygenates
T Mizugaki, K Kaneda - The Chemical Record, 2019 - Wiley Online Library
The environmental impact of CO2 emissions via the use of fossil resources as chemical
feedstock and fuels has stimulated research to utilize renewable biomass feedstock. The …
feedstock and fuels has stimulated research to utilize renewable biomass feedstock. The …
Valorization of small alkanes by biocatalytic oxyfunctionalization
The oxidation of alkanes into valuable chemical products is a vital reaction in organic
synthesis. This reaction, however, is challenging, owing to the inertness of C− H bonds …
synthesis. This reaction, however, is challenging, owing to the inertness of C− H bonds …
Nickel-catalyzed reductive cleavage of carbon–oxygen bonds in anisole derivatives using diisopropylaminoborane
T Igarashi, A Haito, N Chatani, M Tobisu - ACS Catalysis, 2018 - ACS Publications
The catalytic removal of a methoxy group on an aromatic ring allows this group to be used
as a traceless activating and directing group for aromatic functionalization reactions …
as a traceless activating and directing group for aromatic functionalization reactions …
Selective production of linear α-olefins via catalytic deoxygenation of fatty acids and derivatives
A Chatterjee, SHH Eliasson, VR Jensen - Catalysis Science & …, 2018 - pubs.rsc.org
Scientists are exploring renewables as sources for a more sustainable production of
chemicals. Linear α-olefins (LAOs) are key commodity chemicals and petrochemical …
chemicals. Linear α-olefins (LAOs) are key commodity chemicals and petrochemical …
Direct C− C Double Bond Cleavage of Alkenes Enabled by Highly Dispersed Cobalt Catalyst and Hydroxylamine
The utilization of a single‐atom catalyst to break C− C bonds merges the merits of
homogeneous and heterogeneous catalysis and presents an intriguing pathway for …
homogeneous and heterogeneous catalysis and presents an intriguing pathway for …