Aerobic cleavage of alkenes and alkynes into carbonyl and carboxyl compounds

G Urgoitia, R SanMartin, MT Herrero… - ACS Catalysis, 2017 - ACS Publications
This review provides an overview of the recent developments on the oxygen-mediated
cleavage of olefins and acetylene derivatives to provide carbonyl and carboxylic …

Aerobic oxidative cleavage and esterification of C (OH)–C bonds

M Liu, Z Zhang, J Yan, S Liu, H Liu, Z Liu, W Wang… - Chem, 2020 - cell.com
Summary C (OH)–C bonds are widely distributed in naturally renewable biomass, such as
carbohydrates, lignin, and their platform molecules. Selective cleavage and functionalization …

Catalytic, mild, and selective oxyfunctionalization of linear alkanes: current challenges

M Bordeaux, A Galarneau… - Angewandte Chemie …, 2012 - Wiley Online Library
Selective catalysts for sustainable oxidation of alkanes are highly demanded because of the
abundance of these molecules in the environment, the possibility to transform them into …

Oxidative alkene cleavage by chemical and enzymatic methods

A Rajagopalan, M Lara, W Kroutil - Advanced Synthesis & …, 2013 - Wiley Online Library
The cleavage of alkenes to the corresponding carbonyl products is a widely employed
method in organic synthesis, especially to introduce oxygen functionalities into molecules …

Transition metal-catalyzed oxidative double bond cleavage of simple and bio-derived alkenes and unsaturated fatty acids

P Spannring, PCA Bruijnincx… - Catalysis Science & …, 2014 - pubs.rsc.org
The oxidative cleavage of the CC double bond in unsaturated fatty acids into aldehydes or
carboxylic acids is a reaction of current interest in biomass valorization. The products of this …

Development of High Performance Heterogeneous Catalysts for Selective Cleavage of C− O and C− C Bonds of Biomass‐Derived Oxygenates

T Mizugaki, K Kaneda - The Chemical Record, 2019 - Wiley Online Library
The environmental impact of CO2 emissions via the use of fossil resources as chemical
feedstock and fuels has stimulated research to utilize renewable biomass feedstock. The …

Valorization of small alkanes by biocatalytic oxyfunctionalization

D Mahor, Z Cong, MJ Weissenborn… - …, 2022 - Wiley Online Library
The oxidation of alkanes into valuable chemical products is a vital reaction in organic
synthesis. This reaction, however, is challenging, owing to the inertness of C− H bonds …

Nickel-catalyzed reductive cleavage of carbon–oxygen bonds in anisole derivatives using diisopropylaminoborane

T Igarashi, A Haito, N Chatani, M Tobisu - ACS Catalysis, 2018 - ACS Publications
The catalytic removal of a methoxy group on an aromatic ring allows this group to be used
as a traceless activating and directing group for aromatic functionalization reactions …

Selective production of linear α-olefins via catalytic deoxygenation of fatty acids and derivatives

A Chatterjee, SHH Eliasson, VR Jensen - Catalysis Science & …, 2018 - pubs.rsc.org
Scientists are exploring renewables as sources for a more sustainable production of
chemicals. Linear α-olefins (LAOs) are key commodity chemicals and petrochemical …

Direct C− C Double Bond Cleavage of Alkenes Enabled by Highly Dispersed Cobalt Catalyst and Hydroxylamine

W Xue, Y Jiang, H Lu, B You, X Wang… - Angewandte …, 2023 - Wiley Online Library
The utilization of a single‐atom catalyst to break C− C bonds merges the merits of
homogeneous and heterogeneous catalysis and presents an intriguing pathway for …