Applications of Sharpless asymmetric epoxidation in total synthesis

MM Heravi, TB Lashaki, N Poorahmad - Tetrahedron: Asymmetry, 2015 - Elsevier
This report presents the applications of enantioselective epoxidation of prochiral allylic
alcohols, so called 'Sharpless asymmetric epoxidation', which is frequently referred as …

Applications of sharpless asymmetric dihydroxylation in the total synthesis of natural products

MM Heravi, V Zadsirjan, M Esfandyari… - Tetrahedron: Asymmetry, 2017 - Elsevier
Sharpless asymmetric dihydroxylation involves the reaction of an alkene with osmium
tetroxide in the presence of a chiral quinine ligand to form an optically active vicinal diol …

6-[ω-arylalkenyl]-5, 6-dihydro-α-pyrones from Cryptocarya moschata (Lauraceae)

AJ Cavalheiro, M Yoshida - Phytochemistry, 2000 - Elsevier
Eleven 6-[ω-arylalkenyl]-5, 6-dihydro-α-pyrones, cryptomoscatones D2, E1, E2, E3 and F1
and cryptopyranmoscatones A1, A2, A3, B1, B2 and B4, in addition to goniothalamin and …

Stereoselective syntheses of naturally occurring 5, 6-dihydropyran-2-ones

JA Marco, M Carda, J Murga, E Falomir - Tetrahedron, 2007 - Elsevier
1. Introduction....................................................................... 2930 2. Synthetic methodologies for
dihydropyranones......................................... 2930 2.1. Lactonization of substituted d-hydroxy …

The Kulinkovich hydroxycyclopropanation reaction in natural product synthesis

I Haym, MA Brimble - Organic & Biomolecular Chemistry, 2012 - pubs.rsc.org
The Kulinkovich cyclopropanation reaction provides a flexible and convenient method for
the synthesis of cyclopropanols. Together with the diverse chemistry of the cyclopropanol …

Enzymatic kinetic resolution and chemoenzymatic dynamic kinetic resolution of δ-hydroxy esters. An efficient route to chiral δ-lactones

O Pàmies, JE Bäckvall - The Journal of Organic Chemistry, 2002 - ACS Publications
A successful kinetic resolution of a racemic mixture of δ-hydroxy esters 1 was obtained via
lipase-catalyzed transesterification (E value up to 360). The combination of the enzymatic …

Antimalarial 5,6-Dihydro-α-pyrones from Cryptocarya rigidifolia: Related Bicyclic Tetrahydro-α-Pyrones Are Artifacts1

Y Liu, LH Rakotondraibe, PJ Brodie… - Journal of natural …, 2015 - ACS Publications
Antimalarial bioassay-guided fractionation of an EtOH extract of the root wood of
Cryptocarya rigidifolia (Lauraceae) led to the isolation of the five new 5, 6-dihydro-α-pyrones …

[图书][B] Lipid biotechnology

TM Kuo, H Gardner - 2002 - books.google.com
This text presents the latest advances in supercritical fluid technology, biocatalysis,
bioprocess engineering, and crop breeding. It offers an in-depth review of the most recent …

Cryptocaryols A–H, α-Pyrone-Containing 1,3-Polyols from Cryptocarya sp. Implicated in Stabilizing the Tumor Suppressor Pdcd4

T Grkovic, JS Blees, NH Colburn, T Schmid… - Journal of natural …, 2011 - ACS Publications
A high-throughput cell-based reporter assay designed to identify small-molecule stabilizers
of the tumor suppressor Pdcd4 was used to screen extracts in the NCI Natural Products …

Complementarity of DFT Calculations, NMR Anisotropy, and ECD for the Configurational Analysis of Brevipolides K–O from Hyptis brevipes

GA Suárez-Ortiz, CM Cerda-García-Rojas… - Journal of natural …, 2017 - ACS Publications
Brevipolides K–O (1–5), five new cytotoxic 6-(6′-cinnamoyloxy-2′, 5′-epoxy-1′-
hydroxyheptyl)-5, 6-dihydro-2 H-pyran-2-ones (IC50 values against six cancer cell lines, 1.7 …