Metallization‐Prompted Robust Porphyrin‐Based Hydrogen‐Bonded Organic Frameworks for Photocatalytic CO2 Reduction

Q Yin, EV Alexandrov, DH Si, QQ Huang… - Angewandte …, 2022 - Wiley Online Library
Under topological guidance, the self‐assembly process based on a tetratopic porphyrin
synthon results in a hydrogen‐bonded organic framework (HOF) with the predicted square …

Partial Metalation of Porphyrin Moieties in Hydrogen‐Bonded Organic Frameworks Provides Enhanced CO2 Photoreduction Activity

AA Zhang, D Si, H Huang, L Xie… - Angewandte Chemie …, 2022 - Wiley Online Library
In natural photosynthesis, the architecture of multiproteins integrates more chromophores
than redox centers and simultaneously creates a well‐controlled environment around the …

Two-Dimensional Porphyrin-Based Covalent Organic Framework with Enlarged Inter-layer Spacing for Tunable Photocatalytic CO2 Reduction

X Wang, X Ding, T Wang, K Wang, Y Jin… - … Applied Materials & …, 2022 - ACS Publications
Two-dimensional (2D) porphyrin-based covalent organic frameworks (COFs) are one of the
most promising candidates for photocatalytic carbon dioxide reduction reaction (CO2RR) …

Pyridine‐Based Covalent Organic Frameworks with Pyridyl‐Imine Structures for Boosting Photocatalytic H2O2 Production via One‐Step 2e Oxygen Reduction

W Wu, Z Li, S Liu, D Zhang, B Cai, Y Liang… - Angewandte …, 2024 - Wiley Online Library
Bipyridine‐based covalent organic frameworks (COFs) have emerged as promising
contenders for the photocatalytic generation of hydrogen peroxide (H2O2). However, the …

Stable immobilization of nickel ions on covalent organic frameworks for panchromatic photocatalytic hydrogen evolution

H Zhang, Z Lin, P Kidkhunthod, J Guo - Angewandte Chemie, 2023 - Wiley Online Library
Post‐coordination design on covalent organic frameworks (COFs) is an efficient strategy for
elevating the photocatalytic activity of organic moiety. However, the rigid skeletons and …

Metalloporphyrin-based covalent organic frameworks composed of the electron donor-acceptor dyads for visible-light-driven selective CO2 reduction

H Lv, R Sa, P Li, D Yuan, X Wang, R Wang - Science China Chemistry, 2020 - Springer
The visible-light-driven photocatalytic CO 2 reduction with high efficiency is highly desirable
but challenging. Herein, we present porphyrin-tetraphenylethene-based covalent organic …

Rational Design of Crystalline Covalent Organic Frameworks for Efficient CO2 Photoreduction with H2O

M Lu, J Liu, Q Li, M Zhang, M Liu, JL Wang… - Angewandte …, 2019 - Wiley Online Library
Solar energy‐driven conversion of CO2 into fuels with H2O as a sacrificial agent is a
challenging research field in photosynthesis. Herein, a series of crystalline porphyrin …

A fully conjugated covalent organic framework with oxidative and reductive sites for photocatalytic carbon dioxide reduction with water

YZ Cheng, W Ji, PY Hao, XH Qi, X Wu… - Angewandte Chemie …, 2023 - Wiley Online Library
Constructing a powerful photocatalytic system that can achieve the carbon dioxide (CO2)
reduction half‐reaction and the water (H2O) oxidation half‐reaction simultaneously is a very …

Efficient visible‐light‐driven carbon dioxide reduction by a single‐atom implanted metal–organic framework

H Zhang, J Wei, J Dong, G Liu, L Shi, P An… - Angewandte …, 2016 - Wiley Online Library
Modular optimization of metal–organic frameworks (MOFs) was realized by incorporation of
coordinatively unsaturated single atoms in a MOF matrix. The newly developed MOF can …

Covalent Organic Frameworks as Emerging Platforms for CO2 Photoreduction

HL Nguyen, A Alzamly - ACS Catalysis, 2021 - ACS Publications
Covalent organic frameworks (COFs) are an emerging class of porous crystalline materials
consisting of purely organic linking units stitched by strong covalent bonds to form extended …