Recent advances in the direct synthesis of trifluoromethyl-containing heterocycles from
trifluoroacetimidoyl chlorides (TFAICs) and derivatives, including …

Mechanistic understanding of asymmetric induction plays a crucial role in designing new
catalytic asymmetric reactions. Reported herein is atroposelective access to C–N axially …

A ruthenium (II)-catalyzed C–H activation/annulation reaction of benzoic acids and CF3-
imidoyl sulfoxonium ylides enabled by weak O-coordination has been achieved. A series of …

In recent years, the silver‐catalyzed and silver‐promoted isocyanide reactions have
attracted much attention, due to its efficiency in the formation of diverse new bonds and good …

Comprehensive Summary A thermally‐induced multi‐component reaction of CF3‐
substituted imidoyl sulfoxonium ylides (TFISYs), amines and (triphenylphosphonio) …

Herein, a method to access 3-trifluoromethyl-1, 4-benzoxazines from CF3-imidoyl
sulfoxonium ylides and 2-bromophenols has been demonstrated. This synthetic protocol …

Abstract The synthesis of 4‐(trifluoromethyl)‐2, 3‐dihydrothiazoles from α‐enolic dithioesters
and imidoyl sulfoxonium ylides has been achieved under thermal conditions. This …

A highly efficient cascade Rh (III)‐catalyzed C− H activation/intramolecular chemodivergent
cyclization reaction of N‐carbamoylindoles and sulfoxonium ylides has been successfully …

Two categories of tetrasubstituted phenols were prepared via the cycloaddition reaction of
vinyl sulfoxonnium ylides with cyclopropenones in a switchable manner. Copper carbenoid …

Developing mild and effective synthetic strategies for producing significant molecules
starting from readily available starting materials is indispensable in organic synthesis …