Action plots in action: in-depth insights into photochemical reactivity
Predicting wavelength-dependent photochemical reactivity is challenging. Herein, we revive
the well-established tool of measuring action spectra and adapt the technique to map …
the well-established tool of measuring action spectra and adapt the technique to map …
Photochemical action plots reveal the fundamental mismatch between absorptivity and photochemical reactivity
Over the last years, the authors' laboratory has employed monochromatic tuneable laser
systems to reveal a fundamental mismatch between the absorptivity of a chromophore and …
systems to reveal a fundamental mismatch between the absorptivity of a chromophore and …
Wavelength dependence of light-induced cycloadditions
The wavelength-dependent conversion of two rapid photoinduced ligation reactions, ie, the
light activation of o-methylbenzaldehydes, leading to the formation of reactive o …
light activation of o-methylbenzaldehydes, leading to the formation of reactive o …
Predicting wavelength-dependent photochemical reactivity and selectivity
Predicting the conversion and selectivity of a photochemical experiment is a conceptually
different challenge compared to thermally induced reactivity. Photochemical transformations …
different challenge compared to thermally induced reactivity. Photochemical transformations …
From a one-mode to a multi-mode understanding of conical intersection mediated ultrafast organic photochemical reactions
Y Boeije, M Olivucci - Chemical Society Reviews, 2023 - pubs.rsc.org
Over the last few decades, conical intersections (CoIns) have grown from theoretical
curiosities into common mechanistic features of photochemical reactions, whose function is …
curiosities into common mechanistic features of photochemical reactions, whose function is …
A beginners guide to understanding the mechanisms of photochemical reactions: things you should know if light is one of your reagents
JC Scaiano - Chemical Society Reviews, 2023 - pubs.rsc.org
The increasing popularity of applied photochemistry has changed the composition of the
practitioners of photochemistry, from traditional specialists, to users whose expertise lies …
practitioners of photochemistry, from traditional specialists, to users whose expertise lies …
Automatic discovery of photoisomerization mechanisms with nanosecond machine learning photodynamics simulations
Photochemical reactions are widely used by academic and industrial researchers to
construct complex molecular architectures via mechanisms that often require harsh reaction …
construct complex molecular architectures via mechanisms that often require harsh reaction …
Photoswitches: from molecules to materials
MM Russew, S Hecht - Advanced Materials, 2010 - Wiley Online Library
Small organic molecules, capable of undergoing efficient and reversible photochemical
reactions to switch them between (at least) two (meta) stable isomers associated with …
reactions to switch them between (at least) two (meta) stable isomers associated with …
A look inside the black box of machine learning photodynamics simulations
J Li, SA Lopez - Accounts of Chemical Research, 2022 - ACS Publications
Conspectus Photochemical reactions are of great importance in chemistry, biology, and
materials science because they take advantage of a renewable energy source, mild reaction …
materials science because they take advantage of a renewable energy source, mild reaction …