Action plots in action: in-depth insights into photochemical reactivity

IM Irshadeen, SL Walden, M Wegener… - Journal of the …, 2021 - ACS Publications
Predicting wavelength-dependent photochemical reactivity is challenging. Herein, we revive
the well-established tool of measuring action spectra and adapt the technique to map …

Photochemical action plots reveal the fundamental mismatch between absorptivity and photochemical reactivity

SL Walden, JA Carroll, AN Unterreiner… - Advanced …, 2024 - Wiley Online Library
Over the last years, the authors' laboratory has employed monochromatic tuneable laser
systems to reveal a fundamental mismatch between the absorptivity of a chromophore and …

Wavelength dependence of light-induced cycloadditions

JP Menzel, BB Noble, A Lauer, ML Coote… - Journal of the …, 2017 - ACS Publications
The wavelength-dependent conversion of two rapid photoinduced ligation reactions, ie, the
light activation of o-methylbenzaldehydes, leading to the formation of reactive o …

Predicting wavelength-dependent photochemical reactivity and selectivity

JP Menzel, BB Noble, JP Blinco… - Nature …, 2021 - nature.com
Predicting the conversion and selectivity of a photochemical experiment is a conceptually
different challenge compared to thermally induced reactivity. Photochemical transformations …

[图书][B] Handbook of synthetic photochemistry

A Albini, M Fagnoni - 2010 - books.google.com
Unique in its focus on preparative impact rather than mechanistic details, this handbook
provides an overview of photochemical reactions classed according to the structural feature …

From a one-mode to a multi-mode understanding of conical intersection mediated ultrafast organic photochemical reactions

Y Boeije, M Olivucci - Chemical Society Reviews, 2023 - pubs.rsc.org
Over the last few decades, conical intersections (CoIns) have grown from theoretical
curiosities into common mechanistic features of photochemical reactions, whose function is …

A beginners guide to understanding the mechanisms of photochemical reactions: things you should know if light is one of your reagents

JC Scaiano - Chemical Society Reviews, 2023 - pubs.rsc.org
The increasing popularity of applied photochemistry has changed the composition of the
practitioners of photochemistry, from traditional specialists, to users whose expertise lies …

Automatic discovery of photoisomerization mechanisms with nanosecond machine learning photodynamics simulations

J Li, P Reiser, BR Boswell, A Eberhard, NZ Burns… - Chemical …, 2021 - pubs.rsc.org
Photochemical reactions are widely used by academic and industrial researchers to
construct complex molecular architectures via mechanisms that often require harsh reaction …

Photoswitches: from molecules to materials

MM Russew, S Hecht - Advanced Materials, 2010 - Wiley Online Library
Small organic molecules, capable of undergoing efficient and reversible photochemical
reactions to switch them between (at least) two (meta) stable isomers associated with …

A look inside the black box of machine learning photodynamics simulations

J Li, SA Lopez - Accounts of Chemical Research, 2022 - ACS Publications
Conspectus Photochemical reactions are of great importance in chemistry, biology, and
materials science because they take advantage of a renewable energy source, mild reaction …