[PDF][PDF] Spectra and dynamics of coupled vibrations in polyatomic molecules

M Quack - Annual Review of Physical Chemistry, 1990 - ir.ethz.ch
The spectra and dynamics of coupled vibrational states in polyatomic molecules have for a
long time been a central theme of physical chemical research (1-3). Recently, a major …

Multiple intermolecular bend vibrational excitation of a hydrogen bond: An extended infrared study of OCOHF

DJ Nesbitt, CM Lovejoy - The Journal of chemical physics, 1990 - pubs.aip.org
We report the use of near infrared tunable difference frequency laser absorption methods to
investigate low‐frequency bending of the intermolecular hydrogen bond in OCOHF …

Statistical intramolecular vibrational relaxation and its hindrance: The fundamentals of (CH3)3C–C≡CH and (CH3)3Si–C≡CH

KK Lehmann, BH Pate, G Scoles - The Journal of Chemical Physics, 1990 - pubs.aip.org
We have measured the fundamental acetylenic C–H stretch near 3.0 μm of (CH3) 3C–C≡
CH and (CH3) 3Si–C≡ CH using an optothermal, molecular beam spectrometer. We find …

Infrared spectra of the ν2 and ν16 bands in the methyl stretch region of jet-cooled 1-butyne

GA Bethardy, DS Perry - Journal of Molecular Spectroscopy, 1990 - Elsevier
Rotationally resolved infrared spectra of the ν 2 and ν 16 bands in the methyl stretch region
of jet-cooled 1-butyne are reported at a resolution of 0.02 cm− 1. Spectra at rotational …

Eigenstate-resolved ν 1 spectrum of CF 3 CCH: anharmonic couplings to the bath

KK Lehmann, BH Pate, G Scoles - Journal of the Chemical Society …, 1990 - pubs.rsc.org
Using the optothermal technique we have measured the ν1 fundamental of CF3CCH in a
collimated molecular beam. A linear least-squares fit to the unperturbed K subbands with the …

Temperature dependence of picosecond time resolved fluorescence depletion measurements

PG Smith, JD McDonald - The Journal of chemical physics, 1990 - pubs.aip.org
This paper presents the results of a temperature dependence study of time resolved
fluorescence depletion (TRFD) measurements of intramolecular vibrational energy …