Using the optothermal method for molecular beam, infrared spectroscopy, we have
measured both the fundamental and first overtone of the acetylenic C–H stretch in CF3CCH …

The anharmonic mixing of highly excited vibrational states of HFCO above its dissociation
threshold is studied by stimulated emission pumping spectroscopy. At 0.05-cm-I resolution …

Rotationally resolved fluorescence excitation spectra of three vibronic bands in the S 1← S 0
transitions of 1‐and 2‐methylnaphthalene (1 and 2MN) have been obtained. Each band …

The high‐resolution infrared spectrum of 2‐fluoroethanol (2FE) in a molecular beam was
obtained in the region of 2990–2977 cm− 1. This spectral region contains the asymmetric …

The generation of continuously tunable, cw 1.2–2.2 μm light by the difference mixing of a cw
Nd: YAG lase from a cw ring laser in temperature phase matched LiNbO 3 is described. The …

Selectivity of product formation in activated chemical reactions can be accomplished by the
control of energy acquisition, storage and disposal in the molecular system. This goal can be …

Using frequency resolved techniques we have been able to measure the rate of
intramolecular vibrational energy redistribution in a number of substituted acetylenes. The …

Intramolecular vibrational energy redistribution (IVR) continues to be a subject of wide
interest to chemical physics. Most previous work has found that NR is rapid (on the time …

Conclusion The optical model is based on the distinction between those molecules that are
scattered promptly off the surface and those that are not. The sticking probability is computed …

Intramolecular vibrational energy redistribution (IVR) is studied by picosecond time resolved
fluorescence depletion (TRFD), a technique which directly measures the ultrafast relaxation …