Applications of the Cambridge Structural Database to molecular inorganic chemistry

AG Orpen - Acta Crystallographica Section B: Structural Science, 2002 - journals.iucr.org
Applications of the data in the Cambridge Structural Database (CSD) to knowledge
acquisition and fundamental research in molecular inorganic chemistry are reviewed …

Applications of the Cambridge Structural Database in organic chemistry and crystal chemistry

FH Allen, WDS Motherwell - Acta Crystallographica Section B …, 2002 - journals.iucr.org
The Cambridge Structural Database (CSD) and its associated software systems have
formed the basis for more than 800 research applications in structural chemistry …

Life-science applications of the Cambridge Structural Database

R Taylor - Acta Crystallographica Section D: Biological …, 2002 - journals.iucr.org
Several studies show that the molecular geometries and intermolecular interactions
observed in small-molecule crystal structures are relevant to the modelling of in vivo …

[PDF][PDF] Remarkably Stable Tetrahedral Intermediates: Carbinols from Nucleophilic Additions to N–Acylpyrroles

DA Evans, G Borg, KA Scheidt - … Chemie International Edition, 2002 - researchgate.net
Tetrahedral intermediates resulting from the addition of nucleophiles to carboxylic acid
derivatives are important, short-lived species in acyl-transfer reactions.[1] As a result of their …

Tris(trifluoromethyl)borane Carbonyl, (CF3)3BCOSynthesis, Physical, Chemical and Spectroscopic Properties, Gas Phase, and Solid State Structure

M Finze, E Bernhardt, A Terheiden… - Journal of the …, 2002 - ACS Publications
Tris (trifluoromethyl) borane carbonyl,(CF3) 3BCO, is obtained in high yield by the solvolysis
of K [B (CF3) 4] in concentrated sulfuric acid. The in situ hydrolysis of a single bonded CF3 …

Crystal engineering using 4, 4′-bipyridyl with di-and tricarboxylic acids

N Shan, AD Bond, W Jones - Crystal engineering, 2002 - Elsevier
The X-ray structures of four co-crystals of 4, 4′-bipyridyl (Bipy) with two dicarboxylic acids
and two tricarboxylic acids are described. A coupling (I) involving O–H⋯ N and C–H⋯ O …

Isolation and structural characterization of 1-zirconacyclopent-3-yne, five-membered cyclic alkynes

N Suzuki, M Nishiura, Y Wakatsuki - Science, 2002 - science.org
Stable five-membered cyclic alkynes were synthesized, isolated, and fully characterized.
Divalent zirconium species, bis (cyclopentadienyl) zirconium (II) equivalent, reacted with (Z) …

Coordination chemistry and bioactivity of some metal complexes containing two isomeric bidentate NS Schiff bases derived from S-benzyldithiocarbazate and the X …

MTH Tarafder, TJ Khoo, KA Crouse, AM Ali, BM Yamin… - Polyhedron, 2002 - Elsevier
Isomeric bidentate ligands having nitrogen–sulfur donor sequence were prepared by
condensing S-benzyldithiocarbazate (SBDTC) with 5-methyl-2-furyladehyde (NS) and 2 …

Study of the Reactivity of 2-Acetyl-, 2-Cyano-, 2-Formyl-, and 2-Vinylphenyl Palladium (II) Complexes. Mono-and Triinsertion of an Isocyanide into the Pd− C Bond. A 2 …

J Vicente, JA Abad, E Martínez-Viviente… - Organometallics, 2002 - ACS Publications
We have studied the reactivity of the complexes [Pd (C6H4X-2) Br (bpy)](bpy= 2, 2 '-
bipyridine; X= C (O) Me (1a), CN (1b), CHO (1c)),[Pd {C6H4CH CH2-2}(PPh3)(bpy)](TfO) …

X-ray structure analysis and the intervalent electron transfer in organic mixed-valence crystals with bridged aromatic cation radicals

SV Lindeman, SV Rosokha, D Sun… - Journal of the American …, 2002 - ACS Publications
X-ray crystallography identifies the aromatic donor group D= 2, 5-dimethoxy-4-methylphenyl
to be a suitable redox center for the construction of organic mixed-valence crystals owing to …