Fingerprint plots of Hirshfeld surfaces were used to locate and analyze the deficiencies in
various methodologies employed in the determination of the relative energies of five …

In line with hybridization theory, allenes A1 have a linear C= C= C skeleton with orthogonal
pairs of substituents.[1] The allene framework is so rigid that even minor deviations from …

Carbophilic Lewis acids can polarize a coordinated π-bond by a slippage mechanism. A
series of stable ylid-or enolate gold complexes of ene-1, 1-diamines not only emulate this …

Dieses Buch geht über die konventionelle Betrachtungsweise der Ergebnisse von
Strukturuntersuchungen weit hinaus: das mittlerweile verfügbare umfangreiche …

The first examples of “pre-aromatic” 1, 2-dihydro-1, 2-azaborine heterocycles have been
structurally characterized, enabling the direct comparison of delocalized bonds of 1, 2 …

A series of new bis (guanidinate) alkoxide Group 3 metal complexes [Ln {(Me3Si) 2NC
(NiPr) 2} 2 (OR)](R= OtBu, Ln= Y, Nd, Sm, Lu; R= OiPr, Ln= Y, Nd, Lu) has been synthesized …

Is it possible to coordinate two donor ligands L to a carbon (0) atom, and what would be the
properties of such a carbon atom? These questions have been of interest to chemists for …

A general route to functionalized pentakis (trifluoromethyl) phenyl (C6 (CF3) 5) derivatives,
promising building blocks for designing novel stable carbenes, radical species, superacids …

Previous studies have established that the major pathway for the first singlet excited state of
1-nitronaphthalene is intersystem crossing to the triplet manifold. In this contribution we …

Migratory insertion of diphenyldiazomethane into both metal− carbon bonds of the bis (alkyl)
and bis (aryl) complexes (C5Me5) 2AnR2 yields the first f-element bis (hydrazonato) …