Transition metal-catalyzed C–H activation reactions: diastereoselectivity and enantioselectivity

R Giri, BF Shi, KM Engle, N Maugel… - Chemical Society Reviews, 2009 - pubs.rsc.org
This critical review discusses historical and contemporary research in the field of transition
metal-catalyzed carbon–hydrogen (C–H) bond activation through the lens of …

Synthesis of 9, 9′-biphenanthryl-10, 10′-bis (oxazoline) s and their preliminary evaluations in the Friedel–Crafts alkylations of indoles with nitroalkenes

S Lin, T You - Tetrahedron, 2009 - Elsevier
Chiral 9, 9′-biphenanthryl-10, 10′-bis (oxazoline) s 6a–d were firstly prepared. These
new chiral compounds were evaluated as ligands for the Friedel–Crafts alkylations of …

Asymmetric desymmetrization of 4, 5-epoxycyclohex-1-ene by enantioselective allylic oxidation

Q Tan, M Hayashi - Organic Letters, 2009 - ACS Publications
Asymmetric desymmetrization of allylic oxidation of 4, 5-epoxycyclohex-1-ene (1) took place
in the presence of 2.5 mol% of Cu (CH3CN) 4PF6 and 3 mol% of chiral N, N-bidentate …

A general and mild copper-catalyzed three-component synthesis of protected homoallyl amines

KK Pasunooti, ML Leow, S Vedachalam, BK Gorityala… - Tetrahedron …, 2009 - Elsevier
A mild and highly efficient copper-catalyzed, one-pot, three-component reaction is
developed for the synthesis of homoallyl amines. Reaction of an aldehyde, a carbamate …

A new route to 2, 2′, 3, 3′-tetrasubstituted binaphthyls

M Widhalm, C Aichinger, K Mereiter - Tetrahedron Letters, 2009 - Elsevier
Based on an ortho-lithiation protocol of 2, 2′-dibromo-1, 1′-binaphthyl four
tetrasubstituted binaphthyls, 2, 2′-dibromo-3, 3′-diiodo-, 3, 3′-dibromo-2, 2′-diiodo-, 2 …

Synthesis of annulated 1, 4-dioxanes and perhydro-1, 4-oxazines by domino-Wacker-carbonylation and domino-Wacker-MizoroKi-Heck reactions

LF Tietze, A Heins, M Soleiman-Beigi, C Raith - 2009 - publications.goettingen-research …
Palladium (II)-catalyzed domino reactions for the formation of 1, 4-dioxanes and perhydro-1,
4-oxazines starting from hydroxy alkenes are described. The domino-Wacker-carbonylation …