Multiblock polymers: Panacea or Pandora's box?
Advances in synthetic polymer chemistry have unleashed seemingly unlimited strategies for
producing block polymers with arbitrary numbers (n) and types (k) of unique sequences of …
producing block polymers with arbitrary numbers (n) and types (k) of unique sequences of …
Defectivity in laterally confined lamella-forming diblock copolymers: thermodynamic and kinetic aspects
We use self-consistent field theory (SCFT) to study the directed self-assembly of laterally
confined diblock copolymers. In this study, we focus on systems in which the self-assembled …
confined diblock copolymers. In this study, we focus on systems in which the self-assembled …
Investigation of the interfacial tension of complex coacervates using field-theoretic simulations
RA Riggleman, R Kumar… - The Journal of chemical …, 2012 - pubs.aip.org
Complex coacervation, a liquid-liquid phase separation that occurs when two oppositely
charged polyelectrolytes are mixed in a solution, has the potential to be exploited for many …
charged polyelectrolytes are mixed in a solution, has the potential to be exploited for many …
Emergence and stability of helical superstructures in ABC triblock copolymers
W Li, F Qiu, AC Shi - Macromolecules, 2012 - ACS Publications
The emergence and stability of superstructured cylindrical phases in frustrated ABC linear
triblock copolymers are investigated by the self-consistent field theory. Our results reveal that …
triblock copolymers are investigated by the self-consistent field theory. Our results reveal that …
Blockiness and sequence polydispersity effects on the phase behavior and interfacial properties of gradient copolymers
We consider the influence of sequence polydispersity upon the phase behavior and
interfacial characteristics of gradient copolymers. By adapting the algorithmic procedure …
interfacial characteristics of gradient copolymers. By adapting the algorithmic procedure …
Parallel algorithm for 3D SCF simulation of copolymers with flexible and rigid blocks
YA Kriksin, PG Khalatur - Macromolecular theory and …, 2012 - Wiley Online Library
Numerical SCFT simulations of inhomogeneous polymers at the mesoscale can easily
become computationally extremely demanding as the size (spatial resolution) of the …
become computationally extremely demanding as the size (spatial resolution) of the …
Long-range ordering of symmetric block copolymer domains by chaining of superparamagnetic nanoparticles in external magnetic fields
A new method to achieve long-range orientational order in symmetric diblock copolymer
nanodomains through the alignment and chaining of superparamagnetic nanoparticles in a …
nanodomains through the alignment and chaining of superparamagnetic nanoparticles in a …
Self-consistent field theory of gaussian ring polymers
We present a self-consistent field theory (SCFT) formalism of topologically unconstrained
ring polymers for the first time. The resulting static properties of homogeneous and …
ring polymers for the first time. The resulting static properties of homogeneous and …
Chebyshev collocation in polymer field theory: application to wetting phenomena
An efficient numerical self-consistent field theory (SCFT) algorithm is developed for polymer
systems subject to nonperiodic boundary conditions. The method involves collocation with a …
systems subject to nonperiodic boundary conditions. The method involves collocation with a …
Phase behaviors and ordering dynamics of diblock copolymer self-assembly directed by lateral hexagonal confinement
The thermodynamics and kinetics of the self-assembly of cylinder-forming diblock
copolymers directed by the lateral confinement of hexagons have been studied by the …
copolymers directed by the lateral confinement of hexagons have been studied by the …