Photoinduced single-molecule magnet properties in a four-coordinate iron (II) spin crossover complex

C Mathonière, HJ Lin, D Siretanu… - Journal of the …, 2013 - ACS Publications
The four-coordinate Fe (II) complex, PhB (MesIm) 3Fe-N PPh3 (1) has been previously
reported to undergo a thermal spin-crossover (SCO) between high-spin (HS, S= 2) and low …

Metal–Metal Interactions in C3-Symmetric Diiron Imido Complexes Linked by Phosphinoamide Ligands

S Kuppuswamy, TM Powers, BM Johnson… - Inorganic …, 2013 - ACS Publications
The tris (phosphinoamide)-bridged FeIIFeII diiron complex Fe (μ-i PrNPPh2) 3Fe (η2-i
PrNPPh2)(1) can be reduced in the absence or presence of PMe3 to generate the mixed …

Employing Dianionic Macrocyclic Tetracarbenes To Synthesize Neutral Divalent Metal Complexes

HM Bass, SA Cramer, AS McCullough… - …, 2013 - ACS Publications
Macrocyclic tetraimidazolium diborate ligand precursors with two different ring sizes have
been synthesized by ring-forming reactions between diimidazoles and haloboranes …

Generation of a high-valent iron imido corrolazine complex and NR group transfer reactivity

P Leeladee, GNL Jameson, MA Siegler… - Inorganic …, 2013 - ACS Publications
The generation of a new high-valent iron terminal imido complex prepared with a
corrolazine macrocycle is reported. The reaction of [FeIII (TBP8Cz)](TBP8Cz= octakis (4-tert …

Spin state modulation of iron spin crossover complexes via hydrogen-bonding self-assembly

MC Young, E Liew, J Ashby, KE McCoy… - Chemical …, 2013 - pubs.rsc.org
Iron complexes derived from 6-diaminotriazyl-2, 2′-bipyridines display spin crossover
behaviour, and hydrogen bonding-controlled self-assembly with a suitable barbiturate …

Comparative insight into electronic properties and reactivities toward C–H bond activation by iron (IV)–nitrido, iron (IV)–oxo, and iron (IV)–sulfido complexes: a …

H Tang, J Guan, H Liu, X Huang - Inorganic Chemistry, 2013 - ACS Publications
A range of novel octahedral iron (IV)–nitrido complexes with the TMC ligand (TMC= 1, 4, 8,
11-tetramethyl-1, 4, 8, 11-tetraazacyclotetradecane) in the equatorial plane and one axial …

Structural, magnetic and calorimetric studies of a crystalline phase of the spin crossover compound [Fe (tzpy) 2 (NCSe) 2]

Z Arcis-Castillo, L Pineiro-Lopez, MC Muñoz… - …, 2013 - pubs.rsc.org
The compound [Fe (tzpy) 2 (NCSe) 2](tzpy= 3-(2-pyridyl)-[1, 2, 3] triazolo [1, 5-a] pyridine))
has been synthesized and its crystal structure, magnetic behavior and calorimetric …

5-Aminotetrazole induces spin crossover in iron (III) pentadentate Schiff base complexes: experimental and theoretical investigations

R Herchel, Z Trávníček - Dalton Transactions, 2013 - pubs.rsc.org
A series of novel mononuclear iron (III) complexes [Fe (saldpt)(atz)](1) and [Fe
(Rsalpet)(atz)](2a–d) involving 5-aminotetrazole (Hatz) and pentadentate Schiff base …

Novel Mononuclear Spin‐Crossover Complexes

B Weber - Spin‐Crossover Materials: Properties and …, 2013 - Wiley Online Library
This chapter on novel mononuclear spin‐crossover (SCO, or spin‐transition, ST) complexes
gives an overview of some new developments since 2003. The overview is limited to …