Mixed AggregAte (MAA): A single concept for all dipolar organometallic aggregates. 2. Syntheses and reactivities of homo/heteroMAAs

F Mongin, A Harrison-Marchand - Chemical Reviews, 2013 - ACS Publications
Mixing two organometallic reagents leads to synergic mixed aggregates or ate complexes
for which we suggest (as well as for oligomers) the name “Mixed AggregAte” or MAA. The …

Group 7 transition metal complexes with N-heterocyclic carbenes

SJ Hock, LA Schaper, WA Herrmann… - Chemical Society …, 2013 - pubs.rsc.org
This tutorial review summarizes all works and highlights recent advances published in the
growing field of group 7 N-heterocyclic carbene (NHC) complexes. It provides a valuable …

Development of new polymerization catalysts with manganese (II) complexes

K Fujisawa, M Nabika - Coordination chemistry reviews, 2013 - Elsevier
Many transition metal catalysts including both early and late transition metal ions have been
investigated for olefin polymerization and copolymerization reactions. Less attention has …

[HTML][HTML] Dibenzyl and diallyl 2, 6-bisiminopyridinezinc (II) complexes: selective alkyl migration to the pyridine ring leads to remarkably stable dihydropyridinates

JJ Sandoval, P Palma, E Álvarez… - Chemical …, 2013 - pubs.rsc.org
Diorganozinc compounds (ZnR2) with R= CH2Ph or CH2CHCH2 react with 2, 6-
bisiminopyridines (iPrBIP) to afford thermally stable dihydropyridinate (− 1) complexes, and …

Transmetalation of chromocene by lithium-amide,-phosphide, and-arsenide nucleophiles

S Scheuermayer, F Tuna, EM Pineda… - Inorganic …, 2013 - ACS Publications
The pnictogen-centered nucleophiles LiE (SiMe3) 2 (E= N, P, or As) substitute a
cyclopentadienide ligand of chromocene (Cp2Cr), with elimination of lithium …

Synthesis of a bis (indenyl) Co (i) anion: a reactive source of a 14 electron indenyl Co (i) equivalent

F Hung-Low, CA Bradley - Inorganic Chemistry, 2013 - ACS Publications
Alkali metal reduction of (η5-C9H5-1, 3-(SiMe3) 2) 2Co (1) in tetrahydrofuran (THF) permits
isolation of the unusual and reactive 20 electron Co (I) anion [Na (THF) 6][(η5-C9H5-1, 3 …

Synthesis and crystal structure determination of Mn (II) Schiff base complexes and their performance in ethene polymerization

A Sood, MT Räisänen, E Aitola, A Sibaouih, E Colacio… - Polyhedron, 2013 - Elsevier
Mn (II) complexes 1–10, of which eight are novel, were prepared in high yields by reacting
MnCl2 with bidentate N, N′-imine-pyridine and N, N′-imine-quinoline-type donor ligands …

Exchange-coupled oxygen-and sulfur-bridged cyclopentadienyl-manganese (II) cages

CA Smith, F Tuna, M Bodensteiner, M Helliwell… - Dalton …, 2013 - pubs.rsc.org
The trimetallic complex [{CpMn (μ-OSiPh3) 2} 2Mn](1) and the heterocubane [CpMn (μ3-
SSiPh3)] 4 (2) are formed by deprotonation of Ph3SiQH (Q= O, S) by manganocene, or by …

Bicyclic guanidinates in mono-and di-valent metal complexes, including group 1/2 and group 1/12 heterometallic systems

MP Coles, PB Hitchcock - Australian Journal of Chemistry, 2013 - CSIRO Publishing
Complexes containing mono-, di-, and mixed mono-/di-valent metal centres supported by
the [hpp]–anion (hppH= 1, 3, 4, 6, 7, 8-hexahydro-2H-pyrimido [1, 2-a] pyrimidine) are …

[图书][B] The Synthesis and Magnetochemistry of Transition and Lanthanide Metal Compounds

C Smith - 2013 - search.proquest.com
The introductory Chapter to this thesis outlines fundamental aspects of 4f lanthanide (III)
coordination chemistry, in particular compounds that possess the intriguing properties of …