Ketenes and other cumulenes as reactive intermediates

AD Allen, TT Tidwell - Chemical Reviews, 2013 - ACS Publications
Reactive intermediates as recognized chemical entities date back for over a century, and
among the earliest examples were simple free radicals, as identified in 1879, when it was …

Solvated-ion-pairing-sensitive molecular bistability based on copper (I)-coordinated pyrimidine ring rotation

M Nishikawa, K Nomoto, S Kume… - Inorganic Chemistry, 2013 - ACS Publications
We describe herein the effect of solvated ion pairing on the molecular motion of a pyrimidine
ring coordinated on a copper center. We synthesized a series of heteroleptic copper (I) …

Synthesis and characterization of dimolybdenum (II) complexes connected by carboxylate linkers

XM Cai, D Höhne, M Köberl, M Cokoja… - …, 2013 - ACS Publications
The dinuclear complex cis-[(CH3CN) 6Mo2 (O2C-Fc) 2 (BF4) 2](2) and the square-shaped
compound [(CH3CN) 4Mo2 (O2C-Fc-CO2)(BF4) 2] 4 (3) can be synthesized by reacting …