Lanthanide single-molecule magnets

DN Woodruff, REP Winpenny, RA Layfield - Chemical reviews, 2013 - ACS Publications
In the early 1990s, great excitement followed the discovery that a molecular transition metal
coordination compound could, at liquid-helium temperatures, retain magnetization for long …

Fine-Tuning the Single-Molecule Magnet Properties of a [Dy(III)-Radical]2 Pair

EM Fatila, M Rouzières, MC Jennings… - Journal of the …, 2013 - ACS Publications
A supramolecular species composed of a pair of nonequivalent Dy (III)–radical complexes
exhibits single-molecule magnet (SMM) properties. The weak effective antiferromagnetic …

Single-Molecule Magnetism in Three Related {CoIII2DyIII2}-Acetylacetonate Complexes with Multiple Relaxation Mechanisms

SK Langley, NF Chilton, B Moubaraki… - Inorganic …, 2013 - ACS Publications
Three new heterometallic complexes with formulas of [DyIII2CoIII2 (OMe) 2 (teaH) 2 (acac) 4
(NO3) 2](1),[DyIII2CoIII2 (OH) 2 (teaH) 2 (acac) 4 (NO3) 2]· 4H2O (2), and [DyIII2CoIII2 …

Luminescent, magnetic and ferroelectric properties of noncentrosymmetric chain-like complexes composed of nine-coordinate lanthanide ions

XL Li, CL Chen, HP Xiao, AL Wang, CM Liu… - Dalton …, 2013 - pubs.rsc.org
Reaction of the chiral ligand (−)-4, 5-pinenepyridyl-2-pyrazine (L) with Ln (hfac) 3· 2H2O
precursors [hfac−= 1, 1, 1, 5, 5, 5-hexafluoroacetylacetonate, Ln= Sm3+ (1), Eu3+ (2), Tb3+ …

Syntheses, structures, and magnetic properties of seven-coordinate lanthanide porphyrinate or phthalocyaninate complexes with Kläui's tripodal ligand

F Gao, MX Yao, YY Li, YZ Li, Y Song… - Inorganic Chemistry, 2013 - ACS Publications
A series of seven-coordinate mononuclear lanthanide (III) complexes of the general formula
[(TPP) Ln (LOEt)]· 0.25 H2O and [(Pc) Ln (LOEt)](Ln3+= Dy3+, Tb3+, Ho3+, and Gd3+; TPP …

Solvent Responsive Magnetic Dynamics of a Dinuclear Dysprosium Single‐Molecule Magnet

M Ren, SS Bao, N Hoshino… - … A European Journal, 2013 - Wiley Online Library
A new dysprosium (III) phosphonate dimer {Dy (notpH4)(NO3)(H2O)} 2⋅ 8 H2O (1)[notpH6=
1, 4, 7‐triazacyclononane‐1, 4, 7‐triyl‐tris (methylenephosphonic acid)] that contains two …

Squaring the cube: a family of octametallic lanthanide complexes including a Dy 8 single-molecule magnet

M Fang, H Zhao, AV Prosvirin, D Pinkowicz… - Dalton …, 2013 - pubs.rsc.org
A series of isostructural octanuclear lanthanide complexes of general formula [Ln8 (sao) 4
(μ3-OH) 4 (NO3) 12 (DMF) 12](Ln= Nd (1), Sm (2), Eu (3), Gd (4), Tb (5), Dy (6), Ho (7), Er …

End-on azido-bridged 3d–4f complexes showing single-molecule-magnet property

XC Huang, C Zhou, HY Wei, XY Wang - Inorganic Chemistry, 2013 - ACS Publications
End-On Azido-Bridged 3d–4f Complexes Showing Single-Molecule-Magnet Property |
Inorganic Chemistry ACS ACS Publications C&EN CAS Find my institution Log In Inorganic …

Hydrazone-based dysprosium single molecule magnets

P Zhang, L Zhang, J Tang - Current Inorganic Chemistry …, 2013 - ingentaconnect.com
The discovery of a series of lanthanide complexes behaving as Single Molecule Magnets
(SMMs) has resulted in the rapid expansion of this field in the past few years. In this review …

Transporte cuántico y magnetismo en sistemas inorgánicos: un estudio computacional

DA Aravena Ponce - 2013 - diposit.ub.edu
[spa] En esta tesis doctoral se presentan estudios computacionales basados en métodos de
estructura electrónica de propiedades magnéticas en sistemas inorgánicos moleculares y …