Equatorially coordinated lanthanide single ion magnets

P Zhang, L Zhang, C Wang, S Xue… - Journal of the …, 2014 - ACS Publications
The magnetic relaxation dynamics of low-coordinate DyIII and ErIII complexes, namely three-
coordinate ones with an equatorially coordinated triangle geometry and five-coordinate …

Coupling strategies to enhance single-molecule magnet properties of erbium–cyclooctatetraenyl complexes

JJ Le Roy, L Ungur, I Korobkov… - Journal of the …, 2014 - ACS Publications
Two different coupling strategies were employed to create ErIII single-molecule magnets
(SMMs) using high blocking temperature mononuclear precursors. The magnetic properties …

Field-induced slow magnetic relaxation in cobalt (II) compounds with pentagonal bipyramid geometry

XC Huang, C Zhou, D Shao, XY Wang - Inorganic Chemistry, 2014 - ACS Publications
Field-Induced Slow Magnetic Relaxation in Cobalt(II) Compounds with Pentagonal
Bipyramid Geometry | Inorganic Chemistry ACS ACS Publications C&EN CAS Find my …

A mononuclear transition metal single-molecule magnet in a nuclear spin-free ligand environment

MS Fataftah, JM Zadrozny, DM Rogers… - Inorganic …, 2014 - ACS Publications
The high-spin pseudotetrahedral complex [Co (C3S5) 2] 2–exhibits slow magnetic
relaxation in the absence of an applied dc magnetic field, one of a small number of …

Rational Electrostatic Design of Easy‐Axis Magnetic Anisotropy in a ZnII–DyIII–ZnII Single‐Molecule Magnet with a High Energy Barrier

I Oyarzabal, J Ruiz, JM Seco… - … A European Journal, 2014 - Wiley Online Library
Two novel trinuclear complexes [ZnCl (μ‐L) Ln (μ‐L) ClZn][ZnCl3 (CH3OH)]⋅ 3 CH3OH
(LnIII= Dy (1) and Er (2)) have been prepared from the compartmental ligand N, N …

Synthesis, structure, and magnetic and electrochemical properties of quasi-linear and linear iron (I), cobalt (I), and nickel (I) amido complexes

CY Lin, JC Fettinger, F Grandjean, GJ Long… - Inorganic …, 2014 - ACS Publications
Three potassium crown ether salts,[K (Et2O) 2 (18-crown-6)][Fe {N (SiMe3) Dipp} 2](1a;
Dipp= C6H3-2, 6-Pri2),[K (18-crown-6)][Fe {N (SiMe3) Dipp} 2]· 0.5 PhMe (1b), and [K (18 …

Nickel(II)–Lanthanide(III) Magnetic Exchange Coupling Influencing Single‐Molecule Magnetic Features in {Ni2Ln2} Complexes

N Ahmed, C Das, S Vaidya, SK Langley… - … A European Journal, 2014 - Wiley Online Library
Abstract Four isostructural [Ni2Ln2 (CH3CO2) 3 (HL) 4 (H2O) 2] 3+(Ln3+= Dy (1), Tb (2), Ho
(3) or Lu (4)) complexes and a dinuclear [NiGd (HL) 2 (NO3) 3](5) complex are reported …

Self‐Assembly of a 3d–5f Trinuclear Single‐Molecule Magnet from a Pentavalent Uranyl Complex

L Chatelain, JPS Walsh, J Pécaut, F Tuna… - Angewandte …, 2014 - Wiley Online Library
Mixed‐metal uranium compounds are very attractive candidates in the design of single‐
molecule magnets (SMMs), but only one 3d–5f hetero‐polymetallic SMM containing a …

Dipole-mediated rectification of intramolecular photoinduced charge separation and charge recombination

D Bao, S Upadhyayula, JM Larsen, B Xia… - Journal of the …, 2014 - ACS Publications
Controlling charge transfer at a molecular scale is critical for efficient light harvesting, energy
conversion, and nanoelectronics. Dipole-polarization electrets, the electrostatic analogue of …

Magnetic resonance properties of actinyl carbonate complexes and plutonyl (VI)-tris-nitrate

F Gendron, B Pritchard, H Bolvin… - Inorganic …, 2014 - ACS Publications
Electronic structures and magnetic properties of actinyl ions AnO2 n+(An= U, Np, and Pu)
and the equatorially coordinated carbonate complexes [UO2 (CO3) 3] 5–,[NpO2 (CO3) 3] 4 …