Analysis of the Role of Peripheral Ligands Coordinated to ZnII in Enhancing the Energy Barrier in Luminescent Linear Trinuclear Zn‐Dy‐Zn Single‐Molecule Magnets
JP Costes, S Titos‐Padilla, I Oyarzabal… - … A European Journal, 2015 - Wiley Online Library
Three new Dy complexes have been prepared according to a complex‐as‐ligand strategy.
Structural determinations indicate that the central Dy ion is surrounded by two LZn units (L2 …
Structural determinations indicate that the central Dy ion is surrounded by two LZn units (L2 …
Exchange interaction between multiplets
N Iwahara, LF Chibotaru - Physical Review B, 2015 - APS
Analytical expressions for the exchange interaction between J multiplets of interacting
metallic centers are derived on the basis of a complete electronic model which includes the …
metallic centers are derived on the basis of a complete electronic model which includes the …
Increasing the effective energy barrier promoted by the change of a counteranion in a Zn–Dy–Zn SMM: slow relaxation via the second excited state
The trinuclear complex [ZnCl (μ-L) Dy (μ-L) ClZn] PF6 exhibits a single-molecule magnetic
behaviour under zero field with a relatively large effective energy barrier of 186 cm− 1. Ab …
behaviour under zero field with a relatively large effective energy barrier of 186 cm− 1. Ab …
Origin of Dissimilar Single-Molecule Magnet Behavior of Three MnII2MoIII Complexes Based on [MoIII (CN) 7] 4–Heptacyanomolybdate: Interplay of MoIII–CN–MnII …
VS Mironov - Inorganic Chemistry, 2015 - ACS Publications
The origin of contrasting single-molecule magnet (SMM) behavior of three MnII2MoIII
complexes based on [MoIII (CN) 7] 4–heptacyanomolybdate is analyzed; only the apical …
complexes based on [MoIII (CN) 7] 4–heptacyanomolybdate is analyzed; only the apical …
Single-molecule magnet behaviour in polynuclear assembly of trivalent cerium ions with polyoxomolybdates
AB Khélifa, MS Belkhiria, G Huang, S Freslon… - Dalton …, 2015 - pubs.rsc.org
An isopolyoxomolybdate-based POM is coordinated to trivalent cerium ions to afford a
hybrid complex namely,[Ce (dmso) 8][Ce (η2-NO3) 2 (dmso) 4 (α-Mo8O26) 0.5][Mo6O19] …
hybrid complex namely,[Ce (dmso) 8][Ce (η2-NO3) 2 (dmso) 4 (α-Mo8O26) 0.5][Mo6O19] …
Ising exchange interaction in lanthanides and actinides
LF Chibotaru, N Iwahara - New Journal of Physics, 2015 - iopscience.iop.org
The Ising exchange interaction is a limiting case of strong exchange anisotropy and
represents a key property of many magnetic materials. Here we find the necessary and …
represents a key property of many magnetic materials. Here we find the necessary and …
[HTML][HTML] Structural, magnetic and luminescent properties of lanthanide complexes with N-salicylideneglycine
A series of anionic heavy lanthanide complexes, involving the N-salicylideneglycinato (2-)
Schiff base ligand (salgly) and having the general formula K [Ln (salgly) 2 (H 2 O) 2]∙ H 2 O …
Schiff base ligand (salgly) and having the general formula K [Ln (salgly) 2 (H 2 O) 2]∙ H 2 O …
Mononuclear Lanthanide Complexes: Use of the Crystal Field Theory to Design Single‐Ion Magnets and Spin Qubits
JM Clemente‐Juan, E Coronado… - … and Actinides in …, 2015 - Wiley Online Library
This chapter describes a general theoretical approach that considers a point charge
approximation to calculating the energy spectrum and the wave function of the low‐lying …
approximation to calculating the energy spectrum and the wave function of the low‐lying …
[HTML][HTML] Systematic studies on 3d-3d and 3d-4f multimetallic complexes with interesting magnetic and/or luminescent properties
IO Epelde - 2015 - dialnet.unirioja.es
Resumen" El Magnetismo Molecular y Fotoquímica son las áreas de investigación en las
que se centra el trabajo presentado en esta tesis. El objetivo de este trabajo no sólo ha sido …
que se centra el trabajo presentado en esta tesis. El objetivo de este trabajo no sólo ha sido …
Systematic studies on 3d-3d and 3d-4f multimetallic complexes with interesting magnetic and/or luminescent properties
I Oyarzabal Epelde - 2015 - addi.ehu.es
Abstract El Magnetismo Molecular y Fotoquímica son las áreas de investigación en las que
se centra el trabajo presentado en esta tesis. El objetivo de este trabajo no sólo ha sido la …
se centra el trabajo presentado en esta tesis. El objetivo de este trabajo no sólo ha sido la …