Cluster-based single-molecule magnets

CJ Milios, REP Winpenny - Molecular Nanomagnets and Related …, 2015 - Springer
This review covers single-molecule magnets, not only focussing on developments since
2005 but also including coverage of earlier work where necessary for understanding of …

Disentangling intricate web of interrelated notions at the interface between the physical (crystal field) Hamiltonians and the effective (spin) Hamiltonians

C Rudowicz, M Karbowiak - Coordination Chemistry Reviews, 2015 - Elsevier
This review provides a summary of distinct Hamiltonians used to describe magnetic and
spectroscopic properties of paramagnetic and magnetic coordination compounds. Based on …

Magnetic Relaxation in Single‐Electron Single‐Ion Cerium (III) Magnets: Insights from Ab Initio Calculations

SK Singh, T Gupta, L Ungur… - Chemistry–A European …, 2015 - Wiley Online Library
Detailed ab initio calculations were performed on two structurally different cerium (III) single‐
molecule magnets (SMMs) to probe the origin of magnetic anisotropy and to understand the …

Molecular Rare‐Earth‐Metal Hydrides in Non‐Cyclopentadienyl Environments

W Fegler, A Venugopal, M Kramer… - Angewandte Chemie …, 2015 - Wiley Online Library
Molecular hydrides of the rare‐earth metals play an important role as homogeneous
catalysts and as counterparts of solid‐state interstitial hydrides. Structurally well …

Yttrium complexes of arsine, arsenide, and arsinidene ligands

T Pugh, A Kerridge, RA Layfield - … Chemie International Edition, 2015 - Wiley Online Library
Deprotonation of the yttrium–arsine complex [Cp′ 3Y {As (H) 2Mes}](1)(Cp′= η5‐
C5H4Me, Mes= mesityl) by nBuLi produces the μ‐arsenide complex [{Cp′ 2Y [μ‐As (H) …

Multiple single-molecule magnet behaviors in dysprosium dinuclear complexes involving a multiple functionalized tetrathiafulvalene-based ligand

M Feng, F Pointillart, B Lefeuvre, V Dorcet… - Inorganic …, 2015 - ACS Publications
The reaction between the 2-(1-(2, 6-di (pyrazol-1-yl)-4-methylpyridyl)-4, 5-(4, 5-bis
(propylthio)-tetrathiafulvalenyl)-1 H-benzimidazol-2-yl)-pyridine ligand (L) and 2 equiv of Dy …

Switching nuclearity and Co (II) content through stoichiometry adjustment:{Co II 6 Co III 3} and {Co II Co 4 III} mixed valent complexes and a study of their magnetic …

AV Funes, L Carrella, L Sorace, E Rentschler… - Dalton …, 2015 - pubs.rsc.org
We are reporting two new mixed valent Co (II)/Co (III) polynuclear complexes,{CoII6CoIII3}
and {CoIICoIII4}, bearing different amount of Co (II) ions in their cores, through the …

Luminescent single molecule magnets of a series of β-diketone dysprosium complexes

W Chu, Q Sun, X Yao, P Yan, G An, G Li - RSC advances, 2015 - pubs.rsc.org
A series of three luminescent single molecule magnets of β-diketone mononuclear
dysprosium complexes, namely, Dy (tfa) 3 (H2O) 2· Me2CO (1), Dy (tfa) 3 (bpy)(2) and Dy …

Lanthanide Complexes with Multidentate Oxime Ligands as Single‐Molecule Magnets and Atmospheric Carbon Dioxide Fixation Systems

M Hołyńska, R Clérac… - Chemistry–A European …, 2015 - Wiley Online Library
The synthesis, structure, and magnetic properties of five lanthanide complexes with
multidentate oxime ligands are described. Complexes 1 and 2 (1:[La2 (pop) 2 (acac) 4 …

Synthesis, Crystal Structure, and Single‐Molecule Magnetic Properties of a Salen‐type Zn‐Dy‐Zn Complex

PY Shan, HF Li, P Chen, YM Tian… - … für anorganische und …, 2015 - Wiley Online Library
Abstract A Salen‐type [Salen= N, N′‐ethylene bis (salicylideneimine)] mononuclear
lanthanide (III)‐based Zn‐Dy‐Zn complex [Dy (ZnL) 2 (CH3COO) Cl2]· CH2Cl2 (1) was …