Coordination chemistry and metal-involving reactions of amidoximes: Relevance to the chemistry of oximes and oxime ligands
DS Bolotin, NA Bokach, VY Kukushkin - Coordination Chemistry Reviews, 2016 - Elsevier
Although the versatile chemistry of conventional oximes has been extensively reviewed over
the years in both the organic chemistry literature and the coordination chemistry literature …
the years in both the organic chemistry literature and the coordination chemistry literature …
Tetrel bonding interactions
Tetrel (Tr) bonding is first placed into perspective as a σ‐hole bonding interaction with atoms
of the Tr family. An sp3 R4Tr unit has four σ‐holes with which a Lewis base can form a …
of the Tr family. An sp3 R4Tr unit has four σ‐holes with which a Lewis base can form a …
Singlet (phosphino) phosphinidenes are electrophilic
MM Hansmann, R Jazzar… - Journal of the American …, 2016 - ACS Publications
A room-temperature stable (phosphino)-phosphinidene reacts with carbon monoxide, stable
singlet carbenes, including the poor π-accepting imidazol-2-ylidene, and phosphines giving …
singlet carbenes, including the poor π-accepting imidazol-2-ylidene, and phosphines giving …
Time-dependent evolution of the nitrogen configurations in N-doped graphene films
Large-area time-controlled N-doped graphene films were grown on a Cu foil using an
ammonia-assisted atmospheric pressure chemical vapour deposition (APCVD) technique …
ammonia-assisted atmospheric pressure chemical vapour deposition (APCVD) technique …
Difference in Energy between Two Distinct Types of Chalcogen Bonds Drives Regioisomerization of Binuclear (Diaminocarbene)PdII Complexes
The reaction of cis-[PdCl2 (CNXyl) 2](Xyl= 2, 6-Me2C6H3) with various 1, 3-thiazol-and 1, 3,
4-thiadiazol-2-amines in chloroform gives a mixture of two regioisomeric binuclear …
4-thiadiazol-2-amines in chloroform gives a mixture of two regioisomeric binuclear …
Combining the Advantages of Tetrazoles and 1, 2, 3‐Triazoles: 4, 5‐Bis (tetrazol‐5‐yl)‐1, 2, 3‐triazole, 4, 5‐Bis (1‐hydroxytetrazol‐5‐yl)‐1, 2, 3‐triazole, and their …
AA Dippold, D Izsák, TM Klapötke… - Chemistry–A European …, 2016 - Wiley Online Library
In the development of new energetic materials, the main challenge is the combination of
high energy content with chemical and mechanical stability, two properties that are often …
high energy content with chemical and mechanical stability, two properties that are often …
Influence of the 5f orbitals on the bonding and reactivity in organoactinides: experimental and computational studies on a uranium metallacyclopropene
L Zhang, G Hou, G Zi, W Ding… - Journal of the American …, 2016 - ACS Publications
The synthesis, structure, and reactivity of a uranium metallacyclopropene were
comprehensively studied. Reduction of (η5-C5Me5) 2UCl2 (1) with potassium graphite …
comprehensively studied. Reduction of (η5-C5Me5) 2UCl2 (1) with potassium graphite …
Cobalt(II)-Based Single-Ion Magnets with Distorted Pseudotetrahedral [N2O2] Coordination: Experimental and Theoretical Investigations
S Ziegenbalg, D Hornig, H Görls, W Plass - Inorganic Chemistry, 2016 - ACS Publications
The synthesis and magnetic properties of cobalt (II) complexes with sterically demanding
Schiff-base ligands are reported. The compounds [Co (LBr) 2](1) and [Co (LPh) 2]· CH2Cl2 …
Schiff-base ligands are reported. The compounds [Co (LBr) 2](1) and [Co (LPh) 2]· CH2Cl2 …
Chiral carbene–borane adducts: precursors for borenium catalysts for asymmetric FLP hydrogenations
J Lam, BAR Günther, JM Farrell, P Eisenberger… - Dalton …, 2016 - pubs.rsc.org
The carbene derived from (1R, 3S)-camphoric acid was used to prepare the borane adduct
with Piers' borane 7. Subsequent hydride abstraction gave the borenium cation 8. Adducts …
with Piers' borane 7. Subsequent hydride abstraction gave the borenium cation 8. Adducts …
Amido Ln (II) Complexes Coordinated by Bi-and Tridentate Amidinate Ligands: Nonconventional Coordination Modes of Amidinate Ligands and Catalytic Activity in …
IV Basalov, OS Yurova, AV Cherkasov… - Inorganic …, 2016 - ACS Publications
Heteroleptic Ln (II) and Ca (II) amides [t BuC (NC6H3-i Pr2-2, 6) 2] MN (SiMe3) 2 (THF)(M=
Yb (1Yb), Ca (1Ca)),[2-MeOC6H4NC (t Bu) N (C6H3-i Pr2-2, 6)] LnN (SiMe3) 2 (THF)(Ln …
Yb (1Yb), Ca (1Ca)),[2-MeOC6H4NC (t Bu) N (C6H3-i Pr2-2, 6)] LnN (SiMe3) 2 (THF)(Ln …