[HTML][HTML] An air-stable Dy (III) single-ion magnet with high anisotropy barrier and blocking temperature

SK Gupta, T Rajeshkumar, G Rajaraman… - Chemical …, 2016 - pubs.rsc.org
Herein we report air-stable Dy (III) and Er (III) single-ion magnets (SIMs) with pseudo-D5h
symmetry, synthesized from a sterically encumbered phosphonamide, tBuPO (NHiPr) 2 …

Strategies toward high-temperature lanthanide-based single-molecule magnets

L Ungur, LF Chibotaru - Inorganic Chemistry, 2016 - ACS Publications
Lanthanide-based single-molecule magnets are leading materials for achieving
magnetization blocking at the level of one molecule. In this paper, we examine the physical …

[HTML][HTML] The rise of single-ion magnets as spin qubits

YS Ding, YF Deng, YZ Zheng - Magnetochemistry, 2016 - mdpi.com
Recent studies revealed that magnetic molecules with single spin centers showed exciting
phenomena related to quantum information processing, such as long quantum coherence …

Periodic trends in lanthanide compounds through the eyes of multireference ab initio theory

D Aravena, M Atanasov, F Neese - Inorganic Chemistry, 2016 - ACS Publications
Regularities among electronic configurations for common oxidation states in lanthanide
complexes and the low involvement of f orbitals in bonding result in the appearance of …

A planar triangular Dy 3+ Dy 3 single-molecule magnet with a toroidal magnetic moment

XL Li, J Wu, J Tang, B Le Guennic, W Shi… - Chemical …, 2016 - pubs.rsc.org
A planar triangular Dy 3 + Dy 3 single-molecule magnet with a toroidal magnetic moment -
Chemical Communications (RSC Publishing) DOI:10.1039/C6CC05326B Royal Society of …

Coherence and organisation in lanthanoid complexes: from single ion magnets to spin qubits

A Gaita-Arino, H Prima-García… - Inorganic Chemistry …, 2016 - pubs.rsc.org
Molecular magnetism is reaching a degree of development that will allow for the rational
design of sophisticated systems. Among these, here we will focus on those that display …

A scalable architecture for quantum computation with molecular nanomagnets

MD Jenkins, D Zueco, O Roubeau, G Aromí… - Dalton …, 2016 - pubs.rsc.org
A proposal for a magnetic quantum processor that consists of individual molecular spins
coupled to superconducting coplanar resonators and transmission lines is carefully …

[HTML][HTML] Magneto-structural correlations in arsenic-and selenium-ligated dysprosium single-molecule magnets

T Pugh, V Vieru, LF Chibotaru, RA Layfield - Chemical Science, 2016 - pubs.rsc.org
The structures and magnetic properties of the arsenic-and selenium-ligated dysprosium
single-molecule magnets (SMMs)[Cp′ 3Dy (AsH2Mes)](3-Dy),[(η5-Cp′ 2Dy){μ-As (H) …

Effect of Ligand Substitution around the DyIII on the SMM Properties of Dual-Luminescent Zn–Dy and Zn–Dy–Zn Complexes with Large Anisotropy Energy Barriers: A …

JP Costes, S Titos-Padilla, I Oyarzabal… - Inorganic …, 2016 - ACS Publications
The new dinuclear ZnII–DyIII and trinuclear ZnII–DyIII-ZnII complexes of formula [(LZnBrDy
(ovan)(NO3)(H2O)](H2O)· 0.5 (MeOH)(1) and [(L1ZnBr) 2Dy (MeOH) 2](ClO4)(3)(L and L1 …

Physicochemical properties of near-linear lanthanide (II) bis (silylamide) complexes (Ln= Sm, Eu, Tm, Yb)

CAP Goodwin, NF Chilton, GF Vettese… - Inorganic …, 2016 - ACS Publications
Following our report of the first near-linear lanthanide (Ln) complex,[Sm (N††) 2](1), herein
we present the synthesis of [Ln (N††) 2][N††={N (Si i Pr3) 2}; Ln= Eu (2), Tm (3), Yb (4)], thus …