Recent applications of synchrotron radiation and neutrons in the study of soft matter

T Narayanan, H Wacklin, O Konovalov… - Crystallography …, 2017 - Taylor & Francis
The broad range of applications of synchrotron and neutron scattering in the investigation of
soft condensed matter is reviewed. Appropriate combinations of these techniques allow …

Beyond native block copolymer morphologies

GS Doerk, KG Yager - Molecular Systems Design & Engineering, 2017 - pubs.rsc.org
Block copolymers are a well-studied and canonical self-assembly paradigm. Despite active
research, new methods are continually emerging that allow the formation of yet more diverse …

Rapid ordering in “wet brush” block copolymer/homopolymer ternary blends

GS Doerk, KG Yager - ACS nano, 2017 - ACS Publications
The ubiquitous presence of thermodynamically unfavored but kinetically trapped topological
defects in nanopatterns formed via self-assembly of block copolymer thin films may prevent …

Entropy-driven segregation of polymer-grafted nanoparticles under confinement

R Zhang, B Lee, CM Stafford… - Proceedings of the …, 2017 - National Acad Sciences
The modification of nanoparticles with polymer ligands has emerged as a versatile approach
to control the interactions and organization of nanoparticles in polymer nanocomposite …

Thermocapillary approaches to the deliberate patterning of polymers

JP Singer - Journal of Polymer Science Part B: Polymer …, 2017 - Wiley Online Library
The phenomenon of thermocapillarity, the response of fluids to thermal gradients due to
thermal alteration of their surface tension, was first reported over a century ago. Since then …

Thickness-dependence of block copolymer coarsening kinetics

CT Black, C Forrey, KG Yager - Soft Matter, 2017 - pubs.rsc.org
Despite active research, many fundamental aspects of block copolymer ordering remain
unresolved. We studied the thickness-dependence of block copolymer grain coarsening …

Tuning block polymer structure, properties, and processability for the design of efficient nanostructured materials systems

MA Morris, TE Gartner III… - … Chemistry and Physics, 2017 - Wiley Online Library
Block polymers (BPs) are ideal building blocks for nanoporous membranes,
microelectronics templates, energy storage devices, and other technologies. For these …

Numerical simulations of directed self-assembly in diblock copolymer films using zone annealing and pattern templating

JD Hill, PC Millett - Scientific Reports, 2017 - nature.com
Bulk fabrication of surface patterns with sub-20 nm feature sizes is immensely desirable for
many existing and emerging technologies. Directed self-assembly (DSA) of block …

Ordering kinetics of lamella-forming block copolymers under the guidance of various external fields studied by dynamic self-consistent field theory

X Wan, T Gao, L Zhang, J Lin - Physical Chemistry Chemical Physics, 2017 - pubs.rsc.org
Self-consistent field theory with a dynamic extension is exploited to investigate the kinetics of
the lamellar formation of symmetric block copolymers under the direction of external fields. In …

Kinetics of Domain Alignment in Block Polymer Thin Films during Solvent Vapor Annealing with Soft Shear: An in Situ Small-Angle Neutron Scattering Investigation

CK Shelton, RL Jones, TH Epps III - Macromolecules, 2017 - ACS Publications
We employed small-angle neutron scattering (SANS) to identify the kinetic pathways
between disordered and ordered states in block polymer (BP) thin films subjected to solvent …