Efficient Difluoromethylation of Alcohols Using TMSCF2Br as a Unique and Practical Difluorocarbene Reagent under Mild Conditions
Q Xie, C Ni, R Zhang, L Li, J Rong… - Angewandte Chemie …, 2017 - Wiley Online Library
A general method for the efficient difluoromethylation of alcohols using commercially
available TMSCF2Br (TMS= trimethylsilyl) as a unique and practical difluorocarbene source …
available TMSCF2Br (TMS= trimethylsilyl) as a unique and practical difluorocarbene source …
Asymmetric silver-catalysed intermolecular bromotrifluoromethoxylation of alkenes with a new trifluoromethoxylation reagent
S Guo, F Cong, R Guo, L Wang, P Tang - Nature Chemistry, 2017 - nature.com
Fluorinated organic compounds are becoming increasingly important in pharmaceuticals,
agrochemicals and materials science. The introduction of trifluoromethoxy groups into new …
agrochemicals and materials science. The introduction of trifluoromethoxy groups into new …
Enantioselective Construction of Trifluoromethoxylated Stereogenic Centers by a Nickel‐Catalyzed Asymmetric Suzuki–Miyaura Coupling of Secondary Benzyl …
Trifluoromethoxy‐substituted stereogenic centers can be constructed with high
enantioselectivity by a nickel‐catalyzed Suzuki–Miyaura coupling of readily available α …
enantioselectivity by a nickel‐catalyzed Suzuki–Miyaura coupling of readily available α …
Superacid‐Catalyzed Trifluoromethylthiolation of Aromatic Amines
LJC Bonazaba Milandou, H Carreyre… - Angewandte Chemie …, 2017 - Wiley Online Library
Upon activation under superacid conditions, functionalized tailor‐made N‐SCF3
sulfenamides served as reagents for the trifluoromethylthiolation of aromatic amines. This …
sulfenamides served as reagents for the trifluoromethylthiolation of aromatic amines. This …
[HTML][HTML] Selective C–O bond formation via a photocatalytic radical coupling strategy: Access to perfluoroalkoxylated (OR F) arenes and heteroarenes
Development of an efficient process that employs commercially available and cost effective
reagents for the synthesis of perfluoroalkoxylated aromatic compounds (Ar–ORF) remains a …
reagents for the synthesis of perfluoroalkoxylated aromatic compounds (Ar–ORF) remains a …
Tri-and difluoromethoxylated N-based heterocycles− Synthesis and insecticidal activity of novel F3CO-and F2HCO-analogues of Imidacloprid and Thiacloprid
G Landelle, E Schmitt, A Panossian, JP Vors… - Journal of Fluorine …, 2017 - Elsevier
The preparation of F 3 CO-and F 2 HCO-analogues of Imidacloprid and Thiacloprid and the
evaluation of their biological activity have been performed. For this purpose, a first synthetic …
evaluation of their biological activity have been performed. For this purpose, a first synthetic …
Synthesis and physical chemical properties of 2-amino-4-(trifluoromethoxy) butanoic acid–a CF 3 O-containing analogue of natural lipophilic amino acids
IS Kondratov, IG Logvinenko, NA Tolmachova… - Organic & …, 2017 - pubs.rsc.org
Synthesis and physical chemical properties of 2-amino-4-(trifluoromethoxy)butanoic acid –
a CF 3 O-containing analogue of natural lipophilic amino aci ... - Organic & Biomolecular …
a CF 3 O-containing analogue of natural lipophilic amino aci ... - Organic & Biomolecular …
Visible-light-induced installation of oxyfluoroalkyl groups
GR Park, J Moon, EJ Cho - Chemical Communications, 2017 - pubs.rsc.org
(Hetero) aryloxytetrafluoroethylation of heteroaromatics and alkenes has been achieved by
visible-light photocatalysis utilizing readily synthesized oxyfluoroalkyl reagents. The mild …
visible-light photocatalysis utilizing readily synthesized oxyfluoroalkyl reagents. The mild …
Development and biological evaluation of novel fluorinated ingredients for modern crop protection
F Aribi - 2017 - theses.hal.science
This PhD thesis allowed the conception of new molecules for the development of novel
phytosanitary ingredients. First, the synthesis of alpha, alpha-difluoro-betahydroxy ketones …
phytosanitary ingredients. First, the synthesis of alpha, alpha-difluoro-betahydroxy ketones …