Cationic rare-earth metal hydrides

J Okuda - Coordination Chemistry Reviews, 2017 - Elsevier
A survey of the literature on cationic rare-earth metal hydride complexes is presented. This
overview follows systematics based on the nature of supporting ligands and provides …

[HTML][HTML] Cycloheptatrienyl trianion: an elusive bridge in the search of exchange coupled dinuclear organolanthanide single-molecule magnets

KLM Harriman, JJ Le Roy, L Ungur, RJ Holmberg… - Chemical …, 2017 - pubs.rsc.org
The preparation of η-cyclopentadienyl (η5-C5R5), η-arene (η6-C6R6), and η-
cyclooctatetraenyl (η8-C8R8) bridging motifs are common in organometallic chemistry; …

Single-molecule magnets and related phenomena

R Clerac, REP Winpenny - 50 Years of Structure and Bonding–The …, 2017 - Springer
A personal perspective is given of progress in single-molecule magnets (SMMs) and related
phenomena over the last decade. Progress is discussed under seven headings:“Lanthanide …

Complementation and joint contribution of appropriate intramolecular coupling and local ion symmetry to improve magnetic relaxation in a series of dinuclear Dy2 …

HR Tu, WB Sun, HF Li, P Chen, YM Tian… - Inorganic Chemistry …, 2017 - pubs.rsc.org
A series of lanthanide binuclear complexes with formula [Dy2 (DMOP) 2 (NTFA) 4](1),[Dy2
(DMOP) 2 (NTFA) 4 (CH3OH) 2· 2H2O](1a),[Dy2 (DMOP) 2 (BTFA) 4](2),[Dy2 (DMOP) 2 …

Two Series of Homodinuclear Lanthanide Complexes: Greatly Enhancing Energy Barriers through Tuning Terminal Solvent Ligands in Dy2 Single‐Molecule Magnets

Y Qin, H Zhang, H Sun, Y Pan, Y Ge… - Chemistry–An Asian …, 2017 - Wiley Online Library
Abstract The utilization of 2‐ethoxy‐6‐{[(2‐hydroxy‐3‐methoxybenzyl) imino] methyl} phenol
(H2L) as a chelating ligand, in combination with the employment of alcohols (EtOH and …

Unusual undecanuclear heterobimetallic Zn 4 Ln 7 (Ln= Gd, Dy) nano-sized clusters encapsulating two peroxide anions through spontaneous intake of dioxygen

H Ke, X Lu, W Wei, W Wang, G Xie, S Chen - Dalton Transactions, 2017 - pubs.rsc.org
The synthesis, characterization and properties of two unprecedented undecanuclear
heterobimetallic Zn4Ln7 complexes of formula [Zn4Ln7 (L) 8 (O2) 2 (OH) 4 (Cl) 4 (H2O) 4] …

Design of a Family of Ln3 Triangles with the HAT Ligand (1,4,5,8,9,12-Hexaazatriphenylene): Single-Molecule Magnetism

IF Díaz-Ortega, JM Herrera, T Gupta… - Inorganic …, 2017 - ACS Publications
A series of trinuclear Ln3 complexes (LnIII= Yb (1), Er (2), Dy (3) and Gd (4)) were prepared
from the tris-chelate bidentate ligand 1, 4, 5, 8, 9, 12-hexaazatriphenylene (HAT). 1 and 2 …

Rare-earth metal hydrides supported by silicon-bridged boratabenzene fluorenyl ligands: synthesis, structure and reactivity

C Wang, L Xiang, X Leng, Y Chen - Dalton Transactions, 2017 - pubs.rsc.org
The reactions of rare-earth metal benzyl complexes supported by silicon-bridged
boratabenzene fluorenyl ligands with PhSiH3 in toluene gave the corresponding dinuclear …

Lanthanide clusters toward single-molecule magnets

T Han, YS Ding, YZ Zheng - Recent development in clusters of rare earths …, 2017 - Springer
Single-molecule magnets (SMMs) have attracted increasing attention for their potential
applications in high-density information storage and quantum computing. Thereinto …

Ab Initio Investigation of Vibrational, Optical and Thermodynamics Properties of Yttrium Arsenide

S Kansara, D Singh, SK Gupta, Y Sonvane - Journal of Electronic Materials, 2017 - Springer
The paper reports structural, electronic, vibrational, optical, and thermodynamic properties of
the cubic structure of yttrium arsenide (YAs) calculated by density functional calculations …