Inverting the Selectivity of the Newman–Kwart Rearrangement via One Electron Oxidation at Room Temperature

SK Pedersen, A Ulfkjær, MN Newman… - The Journal of …, 2018 - ACS Publications
The discovery that the Newman–Kwart rearrangement can be performed at room
temperature by action of a simple and readily available oxidant, cerium ammonium nitrate, is …

A Rapid Synthesis of Chiral Allylic Amines via Microwave‐assisted Asymmetric Alkenylation of N‐Tosyl Aldimines Catalyzed by Rhodium/Chiral Diene Complexes

B Gopula, HW Zeng, PY Wu… - Journal of the …, 2018 - Wiley Online Library
A method providing expeditious access to chiral allylic amines via a Rh (I)/bicyclo [2.2. 1]
heptadiene‐catalyzed enantioselective alkenylation of N‐tosyl aldimines with potassium …

[PDF][PDF] QUEEN'S UNIVERSITY

A Cummings - 2018 - pure.qub.ac.uk
With the ever-increasing demand for more energy and more" stuff" the majority of which is
derived in some way from fossil fuels, the need to find alternative sources for energy and …