The electronic properties and relatively small size of fluorine endow it with considerable
versatility as a bioisostere and it has found application as a substitute for lone pairs of …

A simple trifluoromethoxylation method enables non‐directed functionalization of C− H
bonds on a range of substrates, providing access to aryl trifluoromethyl ethers. This light …

Trifluoromethyl benzoate (TFBz) is developed as a new shelf-stable trifluoromethoxylation
reagent, which can be easily prepared from inexpensive starting materials using KF as the …

The intermolecular C− H trifluoromethoxylation of arenes remains a long‐standing and
unsolved problem in organic synthesis. Herein, we report the first catalytic protocol …

Organo halides and their derivatives have received much attention in both the design and
development of new synthetic reagents, drugs, and functional materials. In this review, we …

A series of nitrogen-heterocycles have been transformed to the corresponding
trifluoromethyl or higher perfluoroalkyl ethers by reaction of the corresponding N-oxides with …

Air-and light-stable electrophilic difluoromethylating reagents, S-(difluoromethyl)-S-phenyl-S-
(2, 4, 6-trialkoxyphenyl) sulfonium salts were successfully developed, and the introduction of …

The CF 3 O functional group is a unique fluorinated group that has received a great deal of
attention in medicinal chemistry and agrochemistry. However, trifluoromethoxylation of …

Eine einfache Methode für die Trifluormethoxylierung nicht funktionalisierter C‐H‐
Bindungen bietet Zugang zu aromatischen Trifluoromethylethern. Die lichtgetriebene …

US10118890B2 - Trifluoromethoxylation of arenes via intramolecular trifluoromethoxy group
migration - Google Patents US10118890B2 - Trifluoromethoxylation of arenes via intramolecular …