Main group chemistry at the interface with molecular magnetism

FS Guo, AK Bar, RA Layfield - Chemical reviews, 2019 - ACS Publications
Innovative synthetic coordination and, increasingly, organometallic chemistry are at the
heart of advances in molecular magnetism. Smart ligand design is essential for …

Recent advance in heterometallic nanomagnets based on TMxLn4− x cubane subunits

J Wang, M Feng, MN Akhtar, ML Tong - Coordination Chemistry Reviews, 2019 - Elsevier
Abstract 3d-4f cubane-like complexes exhibit unique structural pattern, thus become a
fascinating subclass of 3d-4f complexes. In this review, we first present the structural …

Dehydration–Hydration Switching of Single-Molecule Magnet Behavior and Visible Photoluminescence in a Cyanido-Bridged DyIIICoIII Framework

Y Xin, J Wang, M Zychowicz… - Journal of the …, 2019 - ACS Publications
Microporous magnets compose a class of multifunctional molecule-based materials where
desolvation-driven structural transformation leads to the switching of magnetic properties …

[HTML][HTML] Synthesis, structures and magnetic properties of [(η9-C9H9)Ln(η8-C8H8)] super sandwich complexes

L Muenzfeld, C Schoo, S Bestgen… - Nature …, 2019 - nature.com
Sandwich complexes are an indispensable part of organometallic chemistry, which is
becoming increasingly important in the field of lanthanide-based single molecule magnets …

End-to-End Azido-Bridged Lanthanide Chain Complexes (Dy, Er, Gd, and Y) with a Pentadentate Schiff-Base [N3O2] Ligand: Synthesis, Structure, and Magnetism

TA Bazhenova, VS Mironov, IA Yakushev… - Inorganic …, 2019 - ACS Publications
The syntheses, structure and magnetic properties are reported for five novel 1D polymeric
azido-bridged lanthanide complexes with the general formula {[Ln (DAPMBH)(N3) C2H5OH] …

Purely spectroscopic determination of the spin Hamiltonian parameters in high-spin six-coordinated cobalt (II) complexes with large zero-field splitting

EY Misochko, AV Akimov, DV Korchagin… - Inorganic …, 2019 - ACS Publications
Accurate determination of the spin Hamiltonian parameters in transition-metal complexes
with large zero-field splitting (ZFS) is an actual challenge in studying magnetic and …

Spectroscopic Studies of the Magnetic Excitation and Spin‐Phonon Couplings in a Single‐Molecule Magnet

SE Stavretis, DH Moseley, F Fei, HH Cui… - … A European Journal, 2019 - Wiley Online Library
Large separations between ground and excited magnetic states in single‐molecule magnets
(SMMs) are desirable to reduce the likelihood of spin reversal in the molecules. Spin …

Regulation of Substituent Effects on Configurations and Magnetic Performances of Mononuclear DyIII Single-Molecule Magnets

S Zhang, W Mo, J Zhang, Z Zhang, B Yin, D Hu… - Inorganic …, 2019 - ACS Publications
A series of mononuclear DyIII compounds,[Dy (tmpd) 3 (4, 4′-dmpy)](1),[Dy (tffb) 3 (4, 4′-
dmpy)](2),[Dy (tffb) 3 (5, 5′-dmpy)](3), and [Dy (tmpd) 3 (5, 5′-dmpy)](4)[tmpd= 4, 4, 4 …

Ligand ratio/solvent-influenced syntheses, crystal structures, and magnetic properties of polydentate Schiff base ligand-Dy (III) compounds with β-diketonate ligands …

S Zhang, W Mo, Z Zhang, F Gao, L Wang, D Hu… - Dalton …, 2019 - pubs.rsc.org
Tuning the synthesis conditions and further regulating the magnetic dynamics of single-
molecule magnets (SMMs) are crucial challenges for chemists. Some feasible approaches …

Role of Ab Initio Calculations in the Design and Development of Organometallic Lanthanide‐Based Single‐Molecule Magnets

A Swain, A Sarkar, G Rajaraman - Chemistry–An Asian Journal, 2019 - Wiley Online Library
Single‐molecule magnets based on lanthanides are very attractive due to their potential
applications proposed in the area of microelectronic devices. Very recent advances in this …