Main group chemistry at the interface with molecular magnetism
Innovative synthetic coordination and, increasingly, organometallic chemistry are at the
heart of advances in molecular magnetism. Smart ligand design is essential for …
heart of advances in molecular magnetism. Smart ligand design is essential for …
Recent advance in heterometallic nanomagnets based on TMxLn4− x cubane subunits
J Wang, M Feng, MN Akhtar, ML Tong - Coordination Chemistry Reviews, 2019 - Elsevier
Abstract 3d-4f cubane-like complexes exhibit unique structural pattern, thus become a
fascinating subclass of 3d-4f complexes. In this review, we first present the structural …
fascinating subclass of 3d-4f complexes. In this review, we first present the structural …
Dehydration–Hydration Switching of Single-Molecule Magnet Behavior and Visible Photoluminescence in a Cyanido-Bridged DyIIICoIII Framework
Microporous magnets compose a class of multifunctional molecule-based materials where
desolvation-driven structural transformation leads to the switching of magnetic properties …
desolvation-driven structural transformation leads to the switching of magnetic properties …
[HTML][HTML] Synthesis, structures and magnetic properties of [(η9-C9H9)Ln(η8-C8H8)] super sandwich complexes
L Muenzfeld, C Schoo, S Bestgen… - Nature …, 2019 - nature.com
Sandwich complexes are an indispensable part of organometallic chemistry, which is
becoming increasingly important in the field of lanthanide-based single molecule magnets …
becoming increasingly important in the field of lanthanide-based single molecule magnets …
End-to-End Azido-Bridged Lanthanide Chain Complexes (Dy, Er, Gd, and Y) with a Pentadentate Schiff-Base [N3O2] Ligand: Synthesis, Structure, and Magnetism
TA Bazhenova, VS Mironov, IA Yakushev… - Inorganic …, 2019 - ACS Publications
The syntheses, structure and magnetic properties are reported for five novel 1D polymeric
azido-bridged lanthanide complexes with the general formula {[Ln (DAPMBH)(N3) C2H5OH] …
azido-bridged lanthanide complexes with the general formula {[Ln (DAPMBH)(N3) C2H5OH] …
Purely spectroscopic determination of the spin Hamiltonian parameters in high-spin six-coordinated cobalt (II) complexes with large zero-field splitting
EY Misochko, AV Akimov, DV Korchagin… - Inorganic …, 2019 - ACS Publications
Accurate determination of the spin Hamiltonian parameters in transition-metal complexes
with large zero-field splitting (ZFS) is an actual challenge in studying magnetic and …
with large zero-field splitting (ZFS) is an actual challenge in studying magnetic and …
Spectroscopic Studies of the Magnetic Excitation and Spin‐Phonon Couplings in a Single‐Molecule Magnet
SE Stavretis, DH Moseley, F Fei, HH Cui… - … A European Journal, 2019 - Wiley Online Library
Large separations between ground and excited magnetic states in single‐molecule magnets
(SMMs) are desirable to reduce the likelihood of spin reversal in the molecules. Spin …
(SMMs) are desirable to reduce the likelihood of spin reversal in the molecules. Spin …
Regulation of Substituent Effects on Configurations and Magnetic Performances of Mononuclear DyIII Single-Molecule Magnets
S Zhang, W Mo, J Zhang, Z Zhang, B Yin, D Hu… - Inorganic …, 2019 - ACS Publications
A series of mononuclear DyIII compounds,[Dy (tmpd) 3 (4, 4′-dmpy)](1),[Dy (tffb) 3 (4, 4′-
dmpy)](2),[Dy (tffb) 3 (5, 5′-dmpy)](3), and [Dy (tmpd) 3 (5, 5′-dmpy)](4)[tmpd= 4, 4, 4 …
dmpy)](2),[Dy (tffb) 3 (5, 5′-dmpy)](3), and [Dy (tmpd) 3 (5, 5′-dmpy)](4)[tmpd= 4, 4, 4 …
Ligand ratio/solvent-influenced syntheses, crystal structures, and magnetic properties of polydentate Schiff base ligand-Dy (III) compounds with β-diketonate ligands …
S Zhang, W Mo, Z Zhang, F Gao, L Wang, D Hu… - Dalton …, 2019 - pubs.rsc.org
Tuning the synthesis conditions and further regulating the magnetic dynamics of single-
molecule magnets (SMMs) are crucial challenges for chemists. Some feasible approaches …
molecule magnets (SMMs) are crucial challenges for chemists. Some feasible approaches …
Role of Ab Initio Calculations in the Design and Development of Organometallic Lanthanide‐Based Single‐Molecule Magnets
Single‐molecule magnets based on lanthanides are very attractive due to their potential
applications proposed in the area of microelectronic devices. Very recent advances in this …
applications proposed in the area of microelectronic devices. Very recent advances in this …