Abstract Trifluoromethoxy (OCF3) and difluoromethoxy (OCF2H) groups are fluorinated
structural motifs that exhibit unique physicochemical characteristics. Incorporation of these …

The trifluoromethoxy (CF 3 O) group has become a novel moiety in various fields because of
its unique features. However, despite the promising applications, the synthesis of CF 3 O …

Reported herein is a stereospecific 1, 4‐metallate rearrangement for single‐geometry
ketoxime synthesis from oxime chlorides and arylboronic acids. This strategy exhibits broad …

A series of binary metal complexes [M (L 1) 2] and [M (L 2) 2],(where M= Cu (II), Co (II), Ni
(II)) of Schiff bases, HL 1= 2-((E)-(4-(trifluoromethoxy) phenylimino) methyl)-4-methylphenol …

A facile and practical approach for the difluoromethylation of aliphatic alcohols with an S-
(difluoromethyl) sulfonium salt was developed. A wide variety of alcohols with broad …

A facile and practical approach for the difluoromethylation of phenols and thiophenols was
described. Making use of the recently developed bench-stable S-(difluoromethyl) sulfonium …

Fluorine is probably another favorite hetero-atom for incorporation into small molecules after
nitrogen. Among many fluorine-containing groups, trifluoromethyl aryl ethers (ArOCF 3) have …

A facile and highly efficient approach for selective O-difluoromethylation of 1, 3-diones by
recently developed bench-stable S-(difluoromethyl) sulfonium salt was described. And a …

The organo-catalyzed enantioselective benzylation reaction of α-trifluoromethoxy indanones
afforded α-benzyl-α-trifluoromethoxy indanones with a tetrasubstituted stereogenic carbon …

In the search for an optimal product for modern agricultural chemistry in terms of efficacy,
environmental safety, user friendliness, and economic viability, the substitution of molecules …