Sustainable synthetic approaches involving thiocyanation and sulfur-cyanation: an update

M Gulea, M Donnard - Current Green Chemistry, 2020 - ingentaconnect.com
This review highlights the achievements in the synthesis of organic thiocyanates (OTCs)
over the past five years (late 2015 to mid-2019) and is intended as a follow-up on our tutorial …

Lewis base/Brønsted acid cocatalysis for thiocyanation of amides and thioamides

Qumruddeen, A Yadav, R Kant… - The Journal of Organic …, 2020 - ACS Publications
Lewis base/Brønsted acid cocatalysis for electrophilic thiocyanation of olefins is reported.
Using a combination of triphenylphosphine selenide and diphenyl phosphate as a catalyst …

Metal‐Free Direct C–H Thiolation and Thiocyanation of Pyrazolones

T Kittikool, S Yotphan - European Journal of Organic Chemistry, 2020 - Wiley Online Library
Metal‐free approach for direct C–H thiolation and thiocyanation of N‐substituted
pyrazolones with disulfides and thiocyanate salts, respectively, are developed. These …

Palladium‐catalyzed cyanation of aryl halides using formamide and cyanuric chloride as a new “CN” source

E Niknam, F Panahi… - European Journal of …, 2020 - Wiley Online Library
A new source of “CN” employing formamide and cyanuric chloride is introduced for the
cyanation reactions. The treatment of formamide and 2, 4, 6‐trichloro‐1, 3, 5‐triazine (TCT; …

Selectfluor-initiated cyanation of disulfides to thiocyanates

P Zhou, C Chen, S Li - Journal of Chemical Research, 2020 - journals.sagepub.com
A Selectfluor-initiated cyanation of disulfides to thiocyanates has been developed. In this
process, Selectfluor was employed as the oxidant and trimethylsilyl cyanide was used as the …

Sulfuryl fluoride promoted thiocyanation of alcohols: a practical method for preparing thiocyanates

G Zhang, L Xuan, Y Zhao, C Ding - Synlett, 2020 - thieme-connect.com
A novel SO 2 F 2-promoted thiocyanation method for the one-step synthesis of thiocyanates
through C–O bond cleavage of readily available alcohols with ammonium thiocyanate as the …

Design and Use of Electrophilic Thiocyanating and Selenocyanating Reagents: a New Trend for the Construction of SCN‐and SeCN‐containing Compounds

M Gao, M Vuagnat, MY Chen, X Pannecoucke… - Chemistry-A European …, 2020 - hal.science
Organothiocyanate and organoselenocyanate compounds are of paramount importance in
organic chemistry as they are key intermediates to access sulfur-and selenium-containing …