Mechanisms of asphaltene aggregation: puzzles and a new hypothesis

Y Zhang, M Siskin, MR Gray, CC Walters… - Energy & …, 2020 - ACS Publications
In petroleum science, asphaltenes are well-known as the most refractory fraction of crude oil
and remain infamous for problems in production, transportation, and refining processes …

Overview of asphaltene nanostructures and thermodynamic applications

B Schuler, Y Zhang, F Liu, AE Pomerantz… - Energy & …, 2020 - ACS Publications
Previously, asphaltene science had been hindered by many significant uncertainties
regarding molecular weight, molecular structure, and nanocolloidal characteristics in …

Noncontact atomic force microscopy: Bond imaging and beyond

Q Zhong, X Li, H Zhang, L Chi - Surface Science Reports, 2020 - Elsevier
It was a long-cherished dream for chemists to take a direct look at chemical bonding, a
fundamental component of chemistry. This dream was finally accomplished by the state-of …

Petroleum pitch: Exploring a 50-year structure puzzle with real-space molecular imaging

P Chen, JN Metz, AS Mennito, S Merchant, SE Smith… - Carbon, 2020 - Elsevier
Petroleum pitch has played a significant role in carbon science as a key abundant resource
for polycyclic aromatic hydrocarbons in making various higher value carbon materials …

Investigation of island/single-core-and archipelago/multicore-enriched asphaltenes and their solubility fractions by thermal analysis coupled with high-resolution …

A Neumann, ML Chacon-Patino, RP Rodgers… - Energy & …, 2020 - ACS Publications
Despite extensive research, the molecular-level chemical characterization of asphaltenes, a
highly aromatic solubility fraction of petroleum, remains an analytical challenge. This fraction …

Yen–mullins model applies to oilfield reservoirs

L Chen, A Bertolini, F Dubost, V Achourov… - Energy & …, 2020 - ACS Publications
Fluid distributions throughout oilfield reservoirs have been measured with increasing
accuracy and coverage, both vertical and laterally, in recent years. Currently, a routine …

Experimental and theoretical approach to determine the average asphaltene structure of a crude oil from the golden lane (Faja de Oro) of Mexico

Y Ruiz-Morales, AD Miranda-Olvera… - Energy & …, 2020 - ACS Publications
The structural parameters and average molecular structures of the asphaltenes obtained
from the Aguacate oilfield, located in the Golden Lane of Mexico, have been investigated …

Intramolecular coupling of terminal alkynes by atom manipulation

F Albrecht, D Rey, S Fatayer, F Schulz… - Angewandte …, 2020 - Wiley Online Library
Glaser‐like coupling of terminal alkynes by thermal activation is extensively used in on‐
surface chemistry. Here we demonstrate an intramolecular version of this reaction performed …

Deterring Effect of Resins on the Aggregation of Asphaltenes in n-Heptane

M Derakhshani-Molayousefi, M McCullagh - Energy & Fuels, 2020 - ACS Publications
Asphaltene precipitation can cause clogged pipelines, of which the alleviation costs the oil
industry billions of dollars per year. Asphaltenes are a diverse set of macromolecules native …

Structure-solubility relationships in coal, petroleum, and immature source-rock-derived asphaltenes

KD Bake, PR Craddock, TB Bolin, W Abdallah… - Energy & …, 2020 - ACS Publications
Five asphaltene samples from three different source types–immature source rock (ISA),
petroleum (PA), and coal (CDA)–are studied using integrated chemical and spectroscopic …