Molecular reactions at aqueous interfaces
MF Ruiz-Lopez, JS Francisco… - Nature Reviews …, 2020 - nature.com
This Review aims to critically analyse the emerging field of chemical reactivity at aqueous
interfaces. The subject has evolved rapidly since the discovery of the so-called 'on-water …
interfaces. The subject has evolved rapidly since the discovery of the so-called 'on-water …
Photoinduced oxidation reactions at the air–water interface
JM Anglada, MTC Martins-Costa… - Journal of the …, 2020 - ACS Publications
Chemistry on water is a fascinating area of research. The surface of water and the interfaces
between water and air or hydrophobic media represent asymmetric environments with …
between water and air or hydrophobic media represent asymmetric environments with …
[HTML][HTML] Ultrasonic degradation of perfluorooctane sulfonic acid (PFOS) correlated with sonochemical and sonoluminescence characterisation
Sonolysis has been proposed as a promising treatment technology to remove per-and
polyfluoroalkyl substances (PFASs) from contaminated water. The mechanism of …
polyfluoroalkyl substances (PFASs) from contaminated water. The mechanism of …
Infrared spectroscopy of neutral water clusters at finite temperature: Evidence for a noncyclic pentamer
Infrared spectroscopic study of neutral water clusters is crucial to understanding of the
hydrogen-bonding networks in liquid water and ice. Here we report infrared spectra of size …
hydrogen-bonding networks in liquid water and ice. Here we report infrared spectra of size …
Real-time observation of water radiolysis and hydrated electron formation induced by extreme-ultraviolet pulses
V Svoboda, R Michiels, AC LaForge… - Science …, 2020 - science.org
The dominant pathway of radiation damage begins with the ionization of water. Thus far,
however, the underlying primary processes could not be conclusively elucidated. Here, we …
however, the underlying primary processes could not be conclusively elucidated. Here, we …
Ectoine interaction with DNA: influence on ultraviolet radiation damage
Ectoine is a small zwitterionic osmolyte and compatible solute, which does not interfere with
cell metabolism even at molar concentrations. Plasmid DNA (pUC19) was irradiated with …
cell metabolism even at molar concentrations. Plasmid DNA (pUC19) was irradiated with …
Evaluating Simple Ab Initio Models of the Hydrated Electron: The Role of Dynamical Fluctuations
SJ Park, BJ Schwartz - The Journal of Physical Chemistry B, 2020 - ACS Publications
Despite its importance in electron transfer reactions and radiation chemistry, there has been
disagreement over the fundamental nature of the hydrated electron, such as whether or not it …
disagreement over the fundamental nature of the hydrated electron, such as whether or not it …
Origin of laser-induced colloidal gold surface oxidation and charge density, and its role in oxidation catalysis
Laser fragmentation in liquids (LFL) allows the synthesis of fully inorganic, ultrasmall gold
nanoparticles, usAu NPs (< 3 nm). Although the general method is well established, there is …
nanoparticles, usAu NPs (< 3 nm). Although the general method is well established, there is …
The fluxional nature of the hydrated electron: energy and entropy contributions to aqueous electron free energies
WJ Glover, BJ Schwartz - Journal of Chemical Theory and …, 2020 - ACS Publications
There has been a great deal of recent controversy over the structure of the hydrated electron
and whether it occupies a cavity or contains a significant number of interior waters …
and whether it occupies a cavity or contains a significant number of interior waters …
Water mediated electron attachment to nucleobases: Surface-bound vs bulk solvated electrons
We have presented a mechanism for electron attachment to solvated nucleobases using
accurate wave-function based hybrid quantum/classical (QM/MM) simulations and uracil as …
accurate wave-function based hybrid quantum/classical (QM/MM) simulations and uracil as …