[HTML][HTML] Single-Molecule Magnets: From Mn12-ac to dysprosium metallocenes, a travel in time

A Zabala-Lekuona, JM Seco, E Colacio - Coordination Chemistry Reviews, 2021 - Elsevier
The discovery of the first Single-Molecule Magnet, Mn12-ac, in 1993 changed the
perspective of how information can be stored. The current bit, occupying few hundreds of …

Shining new light on multifunctional lanthanide single‐molecule magnets

R Marin, G Brunet, M Murugesu - … Chemie International Edition, 2021 - Wiley Online Library
Single‐molecule magnets (SMMs) are at the forefront of new technological advances in
quantum information processing and spintronics. Despite the recent impressive …

Air-stable chiral single-molecule magnets with record anisotropy barrier exceeding 1800 K

Z Zhu, C Zhao, T Feng, X Liu, X Ying, XL Li… - Journal of the …, 2021 - ACS Publications
Design and synthesis of air-stable and easily tailored high-performance single-molecule
magnets (SMMs) are of great significance toward the implementation of SMMs in molecular …

A Complete Ab Initio View of Orbach and Raman Spin–Lattice Relaxation in a Dysprosium Coordination Compound

M Briganti, F Santanni, L Tesi, F Totti… - Journal of the …, 2021 - ACS Publications
The unique electronic and magnetic properties of lanthanide molecular complexes place
them at the forefront of the race toward high-temperature single-molecule magnets and …

Ab initio prediction of high-temperature magnetic relaxation rates in single-molecule magnets

D Reta, JGC Kragskow, NF Chilton - Journal of the American …, 2021 - ACS Publications
Organometallic molecules based on [Dy (CpR) 2]+ cations (where CpR is a substituted
cyclopentadienyl anion) have emerged as clear front-runners in the search for high …

Molecular approach to engineer two-dimensional devices for CMOS and beyond-CMOS applications

Y Zhao, M Gobbi, LE Hueso, P Samorì - Chemical Reviews, 2021 - ACS Publications
Two-dimensional materials (2DMs) have attracted tremendous research interest over the
last two decades. Their unique optical, electronic, thermal, and mechanical properties make …

A rare-earth metal retrospective to stimulate all fields

JC Wedal, WJ Evans - Journal of the American Chemical Society, 2021 - ACS Publications
Formulating insightful questions and experiments is crucial to the advancement of science.
The purpose of this Perspective is to encourage scientists in all areas of chemistry to ask …

Mononuclear Dysprosium Alkoxide and Aryloxide Single‐Molecule Magnets

VS Parmar, DP Mills… - Chemistry–A European …, 2021 - Wiley Online Library
Recent studies have shown that mononuclear lanthanide (Ln) complexes can be high‐
performing single‐molecule magnets (SMMs). Recently, there has been an influx of …

Origin of the anomalously low Raman exponents in single molecule magnets

L Gu, R Wu - Physical Review B, 2021 - APS
The Raman exponent of single molecular magnetic relaxation may take various unexpected
values because of rich phonon spectra and spin-phonon coupling of molecular crystals. We …

A journey in lanthanide coordination chemistry: from evaporable dimers to magnetic materials and luminescent devices

K Bernot, C Daiguebonne, G Calvez… - Accounts of Chemical …, 2021 - ACS Publications
Conspectus Lanthanide ions are prime ingredients for the design of compounds, materials,
and devices with unique magnetic and optical properties. Accordingly, coordination …