Relaxation behavior of polymer thin films: Effects of free surface, buried interface, and geometrical confinement
The glass transition temperature (T g) of polymer thin films, one of the most important
parameters to characterize the relaxation behavior of polymer chains in a thin film, has been …
parameters to characterize the relaxation behavior of polymer chains in a thin film, has been …
Direct visualization and characterization of interfacially adsorbed polymer atop nanoparticles and within nanocomposites
Irreversible adsorption at polymer/substrate interfaces has been reported to influence glassy
properties in thin films. However, consideration has yet to be extended to the nanocomposite …
properties in thin films. However, consideration has yet to be extended to the nanocomposite …
Investigation of the atmospheric moisture effect on the molecular behavior of an isocyanate-based primer surface
A primer coating is engineered to facilitate compatibility between products like adhesives,
sealants, and potting compounds and targeted substrates. Prolonged exposure of …
sealants, and potting compounds and targeted substrates. Prolonged exposure of …
Local orientation of chains at crystal/amorphous interfaces buried in isotactic polypropylene thin films
D Kawaguchi, K Yamamoto, T Abe, N Jiang… - Physical Chemistry …, 2021 - pubs.rsc.org
A better understanding of the aggregation states of polymer chains in thin films is of pivotal
importance for developing thin film polymer devices in addition to its inherent scientific …
importance for developing thin film polymer devices in addition to its inherent scientific …
Influence of polymer molecular weight on chain conformation at the polystyrene/silver interface
BM de Lima, PL Hayes, PM Wood-Adams - Langmuir, 2021 - ACS Publications
The dependence between the conformation of polystyrene (PS) and its molecular weight
(Mw) in the vicinity of a metal interface was investigated by sum frequency generation (SFG) …
(Mw) in the vicinity of a metal interface was investigated by sum frequency generation (SFG) …
Temperature and Thickness Dependence of the Time Scale of Crystallization of Polymers under 1D Confinement
Confined in nanodomains, polymers crystallize much slower than in bulk due to both finite
size and interfacial effects. These two factors are successfully disentangled in our …
size and interfacial effects. These two factors are successfully disentangled in our …
Sum Frequency Generation Spectroscopy for Understanding the Polymer Dynamics at Buried Interfaces
D Kawaguchi, K Tanaka - Spectroscopic Techniques for …, 2021 - Wiley Online Library
Vibrational spectroscopy based on sum frequency generation (SFG), which is attained under
a condition that centrosymmery of a medium is broken, is a powerful way to examine static …
a condition that centrosymmery of a medium is broken, is a powerful way to examine static …