Aminocarbyne ligands in organometallic chemistry

L Biancalana, F Marchetti - Coordination Chemistry Reviews, 2021 - Elsevier
Following the former synthetic work on group 6 metal complexes, aminocarbyne
(aminoalkylidyne) ligands have become popular across various transition metal groups …

Bright Chromenylium Polymethine Dyes Enable Fast, Four-Color In Vivo Imaging with Shortwave Infrared Detection

ED Cosco, BA Arús, AL Spearman… - Journal of the …, 2021 - ACS Publications
Optical imaging within the shortwave infrared (SWIR, 1000–2000 nm) region of the
electromagnetic spectrum has enabled high-resolution and high-contrast imaging in mice …

Catalytic reactions directed by a structurally well-defined aminomethyl cyclopalladated complex

H Zhang, T Jiang, J Zhang… - Accounts of Chemical …, 2021 - ACS Publications
Conspectus The introduction of N-containing moieties into feedstock molecules to build
nitrogenated functional molecules has always been widely studied by the organic chemistry …

Overcrowded Ethylene-Bridged Nanohoop Dimers: Regioselective Synthesis, Multiconfigurational Electronic States, and Global Hückel/Möbius Aromaticity

K Li, Z Xu, J Xu, T Weng, X Chen, S Sato… - Journal of the …, 2021 - ACS Publications
The design and preparation of molecular systems with multiple geometric and electronic
configurations are the cornerstones for multifunctional materials with stimuli-responsive …

1, 3, 4‐oxadiazole bridges: A strategy to improve energetics at the molecular level

J Ma, AK Chinnam, G Cheng, H Yang… - Angewandte …, 2021 - Wiley Online Library
Many energetic materials synthesized to date have limited applications because of low
thermal and/or mechanical stability. This limitation can be overcome by introducing structural …

α‐Diazo Sulfonium Triflates: Synthesis, Structure, and Application to the Synthesis of 1‐(Dialkylamino)‐1, 2, 3‐triazoles

X Li, C Golz, M Alcarazo - Angewandte Chemie International …, 2021 - Wiley Online Library
The one‐pot synthesis of a series of sulfonium salts containing transferable diazomethyl
groups is described, and the structure of these compounds is elucidated by X‐ray …

Molecular structure and mild steel/HCl corrosion inhibition of 4, 5-Dicyanoimidazole: Vibrational, electrochemical and quantum mechanical calculations

AM Abuelela, MA Bedair, WM Zoghaib… - Journal of Molecular …, 2021 - Elsevier
Abstract Raman (3500-50 cm− 1) and FT-ATR/FT-infrared (3500-500/4000-200 cm− 1)
spectrum of 4, 5-Dicyanoimidazole (DCI) were recorded and analyzed by normal coordinate …

[HTML][HTML] Crystal, spectroscopic and quantum mechanics studies of Schiff bases derived from 4-nitrocinnamaldehyde

FE Ani, CU Ibeji, NL Obasi, MT Kelani, K Ukogu… - Scientific reports, 2021 - nature.com
Abstract Two Schiff bases,(E)-1-(4-methoxyphenyl)-N-((E)-3-(4-nitrophenyl) allylidene)
methanamine (compound 1) and (E)-N-((E)-3-(4-nitrophenyl) allylidene)-2 …

Revisiting group contribution theory for estimating fractional free volume of microporous polymer membranes

AX Wu, S Lin, KM Rodriguez, FM Benedetti… - Journal of Membrane …, 2021 - Elsevier
Fractional free volume (FFV) is a commonly used metric for the development of structure–
property relationships for polymer membranes. The most common method to calculate FFV …

Molecular dynamics, DFT and electrochemical to study the interfacial adsorption behavior of new imidazo [4, 5-b] pyridine derivative as corrosion inhibitor in acid …

A Saady, E Ech-Chihbi, F El-Hajjaji, F Benhiba… - Journal of Applied …, 2021 - Springer
The present paper discusses the adsorption and inhibitory effect of a new pyridine
derivative, namely, 6-bromo-2-(4-methoxyphenyl)-3-nonyl-3H-imidazo [4, 5-b] pyridine (PIP) …