Mononuclear Dysprosium Alkoxide and Aryloxide Single‐Molecule Magnets

VS Parmar, DP Mills… - Chemistry–A European …, 2021 - Wiley Online Library
Recent studies have shown that mononuclear lanthanide (Ln) complexes can be high‐
performing single‐molecule magnets (SMMs). Recently, there has been an influx of …

Heterometallic CuII–LnIII complexes: Single molecule magnets and magnetic refrigerants

A Dey, P Bag, P Kalita, V Chandrasekhar - Coordination Chemistry …, 2021 - Elsevier
Molecular nanomagnets containing heterometallic 3d-4f complexes have been investigated
extensively for the past few years realizing the role of exchange interaction to minimize the …

Radical‐Bridged Ln4 Metallocene Complexes with Strong Magnetic Coupling and a Large Coercive Field

N Mavragani, D Errulat, DA Gálico, AA Kitos… - Angewandte …, 2021 - Wiley Online Library
Inducing magnetic coupling between 4f elements is an ongoing challenge. To overcome this
formidable difficulty, we incorporate highly delocalized tetrazinyl radicals, which strongly …

Electrophilic trifluoromethylation of dimetallofullerene anions en route to air-stable single-molecule magnets with high blocking temperature of magnetization

Y Wang, G Velkos, NJ Israel… - Journal of the …, 2021 - ACS Publications
Lanthanide dimetallofullerenes with single-electron M–M bonds are an important class of
single molecular magnets and qubit candidates, but stabilization of their unique electronic …

An unusual mechanism of building up of a high magnetization blocking barrier in an octahedral alkoxide Dy 3+-based single-molecule magnet

J Long, AO Tolpygin, E Mamontova… - Inorganic Chemistry …, 2021 - pubs.rsc.org
We report a new octahedral [Dy (OCPh3) 2 (THF) 4][BPh4] luminescent Single-Molecule
Magnet (SMM) exhibiting massive crystal-field splitting and an anisotropic barrier of 1385 …

Synchronous Temperature and Magnetic Field Dual‐Sensing by Luminescence in a Dysprosium Single‐Molecule Magnet

RAS Ferreira, E Mamontova, AMP Botas… - Advanced Optical …, 2021 - Wiley Online Library
Sensors are increasingly present in the everyday life in widespread technological
applications, and engineering smart systems able to simultaneously detect different physical …

Correlating axial and equatorial ligand field effects to the single-molecule magnet performances of a family of dysprosium bis-methanediide complexes

LR Thomas-Hargreaves, MJ Giansiracusa… - Chemical …, 2021 - pubs.rsc.org
Treatment of the new methanediide–methanide complex [Dy (SCS)(SCSH)(THF)](1Dy,
SCS={C (PPh2S) 2} 2−) with alkali metal alkyls and auxillary ethers produces the bis …

Lanthanoid complexes as molecular materials: the redox approach

MA Hay, C Boskovic - Chemistry–A European Journal, 2021 - Wiley Online Library
The development of molecular materials with novel functionality offers promise for
technological innovation. Switchable molecules that incorporate redox‐active components …

Designed polynuclear lanthanide complexes for quantum information processing

D Aguilà, O Roubeau, G Aromí - Dalton Transactions, 2021 - pubs.rsc.org
The design of dissymmetric organic ligands featuring combinations of 1, 3-diketone and 2, 6-
diacetylpyridine coordination pockets has been exploited to produce dinuclear and …

New magnetic and luminescent Dy (III) and Dy (III)/Y (III) based tetranuclear silsesquioxane cages

AN Kulakova, K Nigoghossian, G Félix… - European Journal of …, 2021 - Wiley Online Library
We report here the synthesis, structure, luminescence, and magnetic properties of three new
cage‐like tetranuclear silsesquioxanes (Et4N) 2 [(PhSiO1.. 5) 8 (Y0. 75Dy0. 25O1. 5) 4 …