Heterometallic CuII–LnIII complexes: Single molecule magnets and magnetic refrigerants

A Dey, P Bag, P Kalita, V Chandrasekhar - Coordination Chemistry …, 2021 - Elsevier
Molecular nanomagnets containing heterometallic 3d-4f complexes have been investigated
extensively for the past few years realizing the role of exchange interaction to minimize the …

Switching the magnetic hysteresis of an [Feii–NC–Wv]-based coordination polymer by photoinduced reversible spin crossover

L Zhao, YS Meng, Q Liu, O Sato, Q Shi, H Oshio… - Nature Chemistry, 2021 - nature.com
Magnetic bistable materials that feature magnetic hysteresis are comparable to elementary
binary units and promising for application in switches and memory devices. In this work, we …

Lanthanides and actinides: Annual survey of their organometallic chemistry covering the year 2019

JH Farnaby, T Chowdhury, SJ Horsewill… - Coordination Chemistry …, 2021 - Elsevier
This review summarizes the progress in organo-f-element chemistry during the year 2019.
Organo-f-element chemistry, including Sc, Y, the lanthanides and the actinides, has been a …

A series of dysprosium clusters assembled by a substitution effect-driven out-to-in growth mechanism

HL Wang, T Liu, ZH Zhu, JM Peng, HH Zou… - Inorganic Chemistry …, 2021 - pubs.rsc.org
Although the design and synthesis of high-nuclear lanthanide clusters with specific shapes
and functions have been an active area of research, effective experience and rules to guide …

Tuning magnetic relaxation in square-pyramidal dysprosium single-molecule magnets using apical alkoxide ligands

Z Zhu, YQ Zhang, XL Li, M Guo, J Lu, S Liu… - CCS …, 2021 - chinesechemsoc.org
Eight square-pyramidal dysprosium complexes of the type [Dy (X)(DBP) 2 {TMG (H)} 2] were
synthesized, where TMG (H) denotes 1, 1, 3, 3-tetramethylguanidine, X denotes an alkoxide …

[HTML][HTML] Correlating axial and equatorial ligand field effects to the single-molecule magnet performances of a family of dysprosium bis-methanediide complexes

LR Thomas-Hargreaves, MJ Giansiracusa… - Chemical …, 2021 - pubs.rsc.org
Treatment of the new methanediide–methanide complex [Dy (SCS)(SCSH)(THF)](1Dy,
SCS={C (PPh2S) 2} 2−) with alkali metal alkyls and auxillary ethers produces the bis …

A Series of High-Nuclear Gadolinium Cluster Aggregates with a Magnetocaloric Effect Constructed through Two-Component Manipulation

YL Li, HL Wang, ZH Zhu, J Li, HH Zou… - Inorganic …, 2021 - ACS Publications
The serialized expansion of high-nuclear clusters usually includes the controlled variable
method and changes only a single variable. However, changing both variables will greatly …

Lanthanide-doped topological nanosheets with enhanced near-infrared photothermal performance for energy conversion

Y Huang, G Bai, Y Zhao, Y Liu, S Xu… - ACS Applied Materials & …, 2021 - ACS Publications
Two-dimensional inorganic semiconductor materials have aroused tremendous research
interest and found their potential in resolving the present urgent global issues, such as …

Two C 2v symmetry dysprosium (III) single-molecule magnets with effective energy barriers over 600 K

X Meng, M Wang, X Gou, W Lan, K Jia… - Inorganic Chemistry …, 2021 - pubs.rsc.org
Two mononuclear DyIII single-molecule magnets (SMMs) with C2v coordination symmetry
were synthesized. Both of them have strong uniaxial magnetic anisotropy with high effective …

pH manipulates the assembly of a series of dysprosium clusters with subtle differences

HL Wang, T Liu, ZH Zhu, JM Peng, HH Zou… - Inorganic Chemistry …, 2021 - pubs.rsc.org
When reaction conditions change, products with different shapes and connections are
usually obtained. Thus, the fine-tuning of structures in crystal engineering is challenging. We …